@article{brilliantov98a, title = {Chain collapse and counterion condensation in dilute polyelectrolyte solutions}, author = {N. V. Brilliantov and D. V. Kuznetsov and R. Klein}, journal = {Phys. Rev. Lett.}, number = 7, pages = {1433--1436}, volume = 81, year = 1998, abstract = {A quantitative theory for polyelectrolytes in salt-free dilute solutions is developed. Depending on the electrostatic interaction strength, polyelectrolytes in solutions can undergo strong stretching (with polyelectrolyte dimension R-g similar to l(B)(1/3)N where l(B) is the Bjerrum length and N is the number of the chain segments) or compression (with R-g similar to l(B)(-1/2) N-1/3). A strong polymer collapse occurs as a first-order phase transition due to accompanying counterion condensation.}, biburl = {http://www.bibsonomy.org/bibtex/2ca6e0e125895198955a1fda9a59a63e8/kaigrass}, keywords = {theory. Quantitative polyelectrolytes. Globule. rigid To-coil Interacting Radius. transition.} }