%0 Journal Article %1 Han2002 %A Han, S.-J. %A Lee, C.-W. %A Yoon, H. %A Kang, H. %D 2002 %I AIP %J J. Chem. Phys. %K association; atom-molecule carbon chemistry; compounds; desorption; impact; ion-surface kinetics; oxidation; oxygen; platinum reaction reactions; surface %N 7 %P 2684-2687 %R 10.1063/1.1449948 %T Discovery of COsub 2 precursor in the reaction of CO and O on Pt(111) %U http://link.aip.org/link/?JCP/116/2684/1 %V 116 %X Using the technique of Cs+ reactive ion scattering (Cs+ RIS), we show that reaction of CO and O on a Pt(111) surface produces a CO2 precursor species that remains stable on the surface up to 300 K. The CO2 species desorbs with an activation energy of 46�3 kJ mol�1, whereas the direct CO2 gas formation via Langmuir�Hinshelwood (LH) reaction between CO and O occurs with an activation energy of 75�4 kJ mol�1. The observation reveals a new pathway for CO oxidation reaction, which is different from the direct LH pathway.

@article{Han2002, abstract = {Using the technique of Cs+ reactive ion scattering (Cs+ RIS), we show that reaction of CO and O on a Pt(111) surface produces a CO2 precursor species that remains stable on the surface up to 300 K. The CO2 species desorbs with an activation energy of 46�3 kJ mol�1, whereas the direct CO2 gas formation via Langmuir�Hinshelwood (LH) reaction between CO and O occurs with an activation energy of 75�4 kJ mol�1. The observation reveals a new pathway for CO oxidation reaction, which is different from the direct LH pathway.}, added-at = {2009-10-30T10:04:05.000+0100}, author = {Han, S.-J. and Lee, C.-W. and Yoon, H. and Kang, H.}, biburl = {https://www.bibsonomy.org/bibtex/2b2392cb3218a40960ac6facea4207a81/jfischer}, doi = {10.1063/1.1449948}, interhash = {cda3402f4cbece6e54cf3b9e5ad671a9}, intrahash = {b2392cb3218a40960ac6facea4207a81}, journal = {J. Chem. Phys.}, keywords = {association; atom-molecule carbon chemistry; compounds; desorption; impact; ion-surface kinetics; oxidation; oxygen; platinum reaction reactions; surface}, number = 7, pages = {2684-2687}, publisher = {AIP}, timestamp = {2009-10-30T10:04:13.000+0100}, title = {Discovery of CO[sub 2] precursor in the reaction of CO and O on Pt(111)}, url = {http://link.aip.org/link/?JCP/116/2684/1}, volume = 116, year = 2002 }