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New Wide Band Gap Donor for Efficient Fullerene-Free All-Small-Molecule Organic Solar Cells

, , , , , , , , and . Journal of the American Chemical Society, 139 (5): 1958-1966 (2017)PMID: 28081597.
DOI: 10.1021/jacs.6b11612

Abstract

A new organic small molecule, DRTB-T, that incorporates a two-dimensional trialkylthienyl-substituted benzodithiophene core building block was designed and synthesized. DRTB-T has a band gap (Egopt) of 2.0 eV with a low-lying highest occupied molecular orbital (HOMO) level of −5.51 eV. Nonfullerene small-molecule solar cells consisting of DRTB-T and a nonfullerene acceptor (IC-C6IDT-IC) were constructed, and the morphology of the active layer was fine-tuned by solvent vapor annealing (SVA). The device showed a record 9.08\% power conversion efficiency (PCE) with a high open-circuit voltage (Voc = 0.98 V). This is the highest PCE for a nonfullerene small-molecule organic solar cell (NFSM-OSC) reported to date. Our notable results demonstrate that the molecular design of a wide band gap (WBG) donor to create a well-matched donor–acceptor pair with a low band gap (LBG) nonfullerene small-molecule acceptor, as well as subtle morphological control, provides great potential to realize high-performance NFSM-OSCs.

Description

New Wide Band Gap Donor for Efficient Fullerene-Free All-Small-Molecule Organic Solar Cells - Journal of the American Chemical Society (ACS Publications)

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