Construction of Compact Methylammonium Bismuth Iodide Film Promoting Lead-Free Inverted Planar Heterojunction Organohalide Solar Cells with Open-Circuit Voltage over 0.8 V
A bismuth-based organohalide material, methylammonium bismuth iodide (MA3Bi2I9), has been recently explored as an efficient lead-free light absorber in photovoltaic applications. However, the poor surface morphology of the MA3Bi2I9 film fabricated via conventional one-step spin-coating methods has limited the performance of the device. In this work, a smooth, uniform, and compact MA3Bi2I9 thin film was realized by a novel two-step evaporation–spin-coating film fabrication strategy for the first time. Taking advantage of the superior MA3Bi2I9 thin film, the best-performing inverted planar heterojuncion photovoltaic device exhibited a power conversion efficiency of 0.39\% with open-circuit voltage as high as 0.83 V, which demonstrated the lowest loss-in-potential to date in MA3Bi2I9-based solar cells. Moreover, the facile film fabrication strategy utilized in this work paves the way for high reproducibility of lead-free organohalide films and devices.
%0 Journal Article
%1 doi:10.1021/acs.jpclett.6b02578
%A Ran, Chenxin
%A Wu, Zhaoxin
%A Xi, Jun
%A Yuan, Fang
%A Dong, Hua
%A Lei, Ting
%A He, Xin
%A Hou, Xun
%D 2017
%J The Journal of Physical Chemistry Letters
%K cell lead-free perovskite solar
%N 2
%P 394-400
%R 10.1021/acs.jpclett.6b02578
%T Construction of Compact Methylammonium Bismuth Iodide Film Promoting Lead-Free Inverted Planar Heterojunction Organohalide Solar Cells with Open-Circuit Voltage over 0.8 V
%U http://dx.doi.org/10.1021/acs.jpclett.6b02578
%V 8
%X A bismuth-based organohalide material, methylammonium bismuth iodide (MA3Bi2I9), has been recently explored as an efficient lead-free light absorber in photovoltaic applications. However, the poor surface morphology of the MA3Bi2I9 film fabricated via conventional one-step spin-coating methods has limited the performance of the device. In this work, a smooth, uniform, and compact MA3Bi2I9 thin film was realized by a novel two-step evaporation–spin-coating film fabrication strategy for the first time. Taking advantage of the superior MA3Bi2I9 thin film, the best-performing inverted planar heterojuncion photovoltaic device exhibited a power conversion efficiency of 0.39\% with open-circuit voltage as high as 0.83 V, which demonstrated the lowest loss-in-potential to date in MA3Bi2I9-based solar cells. Moreover, the facile film fabrication strategy utilized in this work paves the way for high reproducibility of lead-free organohalide films and devices.
@article{doi:10.1021/acs.jpclett.6b02578,
abstract = { A bismuth-based organohalide material, methylammonium bismuth iodide (MA3Bi2I9), has been recently explored as an efficient lead-free light absorber in photovoltaic applications. However, the poor surface morphology of the MA3Bi2I9 film fabricated via conventional one-step spin-coating methods has limited the performance of the device. In this work, a smooth, uniform, and compact MA3Bi2I9 thin film was realized by a novel two-step evaporation–spin-coating film fabrication strategy for the first time. Taking advantage of the superior MA3Bi2I9 thin film, the best-performing inverted planar heterojuncion photovoltaic device exhibited a power conversion efficiency of 0.39\% with open-circuit voltage as high as 0.83 V, which demonstrated the lowest loss-in-potential to date in MA3Bi2I9-based solar cells. Moreover, the facile film fabrication strategy utilized in this work paves the way for high reproducibility of lead-free organohalide films and devices. },
added-at = {2017-03-30T08:56:25.000+0200},
author = {Ran, Chenxin and Wu, Zhaoxin and Xi, Jun and Yuan, Fang and Dong, Hua and Lei, Ting and He, Xin and Hou, Xun},
biburl = {https://www.bibsonomy.org/bibtex/211713ae8fe58c58b7e0f0f010fb12de4/woepps},
doi = {10.1021/acs.jpclett.6b02578},
eprint = {http://dx.doi.org/10.1021/acs.jpclett.6b02578},
interhash = {960252910733558d907de7dd60aee474},
intrahash = {11713ae8fe58c58b7e0f0f010fb12de4},
journal = {The Journal of Physical Chemistry Letters},
keywords = {cell lead-free perovskite solar},
note = {PMID: 28048938},
number = 2,
pages = {394-400},
timestamp = {2017-03-30T08:56:25.000+0200},
title = {Construction of Compact Methylammonium Bismuth Iodide Film Promoting Lead-Free Inverted Planar Heterojunction Organohalide Solar Cells with Open-Circuit Voltage over 0.8 V},
url = {http://dx.doi.org/10.1021/acs.jpclett.6b02578},
volume = 8,
year = 2017
}