%0 Journal Article %1 ISI:000253265600016 %A Dehghanpour, Saeed %A Fotouhi, Lida %A Amini, Mostafa Mohammadpour %A Khavasi, Hamid Reza %A Jahani, Khadijeh %A Nouroozi, Fatemeh %A Zamanifar, Elham %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2008 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K complexes; crystal diimine electrochemistry} ligand; structure; {copper(I) %N 3 %P 455-463 %R 10.1080/00958970701360717 %T Synthesis and characterization of Cu(mb(2)en)(2)ClO4 and Cu(mb(2)en)(PPh3)(2)BPh4: crystal structure of Cu(mb(2)en)(2)ClO4 %V 61 %X The ligand, N,N'-bis-(4-methoxy-benzylidene)-ethane-1,2-diamine (mb(2)en), and its corresponding copper(I) complexes, Cu(mb(2)en)(2)ClO4 (1), and Cu(mb(2)en)(PPh3)(2)BPh4 (2), have been synthesized and characterized by CHN analyses, H-1 and C-13-NMR, IR, and UV-Vis spectroscopies. The crystal and molecular structure of Cu(mb(2)en)(2)ClO4 (1), were determined by X-ray crystallography from a single-crystal. The coordination polyhedron about copper(I) is best described as a distorted tetrahedron. Quasi-irreversible redox behavior was observed for 1 and 2 (E-1/2 = 0.55 and 0.95 V, respectively).

@article{ISI:000253265600016, abstract = {{The ligand, N,N'-bis-(4-methoxy-benzylidene)-ethane-1,2-diamine (mb(2)en), and its corresponding copper(I) complexes, {[}Cu(mb(2)en)(2)]ClO4 (1), and {[}Cu(mb(2)en)(PPh3)(2)]BPh4 (2), have been synthesized and characterized by CHN analyses, H-1 and C-13-NMR, IR, and UV-Vis spectroscopies. The crystal and molecular structure of {[}Cu(mb(2)en)(2)]ClO4 (1), were determined by X-ray crystallography from a single-crystal. The coordination polyhedron about copper(I) is best described as a distorted tetrahedron. Quasi-irreversible redox behavior was observed for 1 and 2 (E-1/2 = 0.55 and 0.95 V, respectively).}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Dehghanpour, S (Reprint Author), Alzahra Univ, Dept Chem, Tehran 1993891176, Iran. Dehghanpour, Saeed; Fotouhi, Lida; Jahani, Khadijeh; Nouroozi, Fatemeh; Zamanifar, Elham, Alzahra Univ, Dept Chem, Tehran 1993891176, Iran. Amini, Mostafa Mohammadpour; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Dehghanpour, Saeed and Fotouhi, Lida and Amini, Mostafa Mohammadpour and Khavasi, Hamid Reza and Jahani, Khadijeh and Nouroozi, Fatemeh and Zamanifar, Elham}, author-email = {{Dehganpour\_farasha@yahoo.com}}, biburl = {https://www.bibsonomy.org/bibtex/22d73890fde79b0c2ebbb3f7981027b38/hkhavasi}, cited-references = {{Amirnasr M, 2006, HELV CHIM ACTA, V89, P274, DOI 10.1002/hlca.200690031. Armaroli N, 2001, CHEM SOC REV, V30, P113, DOI 10.1039/b000703j. Bard A. J., 1980, ELECTROCHEMICAL METH. CHOWDHURY S, 2000, J CHEM SOC DA, V3, P235. Cunningham CT, 2000, INORG CHEM, V39, P3638, DOI 10.1021/ic000082s. DEHGHANPOUR S, 2006, Z ANORG ALLG CHEM, V14, P2321. Dehghanpour S, 2007, POLYHEDRON, V26, P154, DOI 10.1016/j.poly.2006.08.011. Dehghanpour S, 2006, STRUCT CHEM, V17, P255, DOI 10.1007/s11224-006-9016-2. DELPAGGIO AA, 1983, INORG CHEM, V22, P691, DOI 10.1021/ic00146a024. Eggleston MK, 1998, J PHYS CHEM A, V102, P5506, DOI 10.1021/jp980059g. Franceschi F, 1997, INORG CHEM, V36, P4099, DOI 10.1021/ic9706156. Hadjikhani R, 2006, Z ANORG ALLG CHEM, V632, P723, DOI 10.1002/zaac.200500489. KUTAL C, 1990, COORDIN CHEM REV, V99, P213, DOI 10.1016/0010-8545(90)80064-Z. Livoreil A, 1997, J AM CHEM SOC, V119, P12114, DOI 10.1021/ja9720826. Luchaco-Cullis CA, 2001, ANGEW CHEM INT EDIT, V40, P1456, DOI 10.1002/1521-3773(20010417)40:8<1456::AID-ANIE1456>3.0.CO;2-T. Meghdadi S, 2002, HELV CHIM ACTA, V85, P2807, DOI 10.1002/1522-2675(200209)85:9<2807::AID-HLCA2807>3.0.CO;2-9. Miller MT, 1999, INORG CHEM, V38, P3414, DOI 10.1021/ic9900399. Miller MT, 1999, INORG CHEM, V38, P5246, DOI 10.1021/ic990588e. Nakamoto K., 1992, INFRARED RAMAN SPECT. Perrin D.D., 1990, PURIFICATION LAB CHE. RADER RA, 1981, J AM CHEM SOC, V103, P5906, DOI 10.1021/ja00409a048. RIKLIN M, 2001, J CHEM SOC DA, V12, P1813. Ruthkosky M, 1998, COORDIN CHEM REV, V171, P309. Sakaki S., 2002, J CHEM SOC DA, V6, P840, DOI {[}10.1039/b109518h, DOI 10.1039/B109518H]. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. {*}STOE CIE, 2004, X SHAPE VES 2 05 PRO. {*}STOE CIE, 2005, XRED VES 1 28B PROGR.}}, doc-delivery-number = {{264DK}}, doi = {{10.1080/00958970701360717}}, interhash = {509bf7385b6089901b43f533b9fa5424}, intrahash = {2d73890fde79b0c2ebbb3f7981027b38}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {complexes; crystal diimine electrochemistry} ligand; structure; {copper(I)}, keywords-plus = {{COPPER(I) COMPLEXES; LIGANDS; PERCHLORATE; SYSTEMS; STATES}}, language = {{English}}, number = {{3}}, number-of-cited-references = {{27}}, pages = {{455-463}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{5}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and characterization of {[}Cu(mb(2)en)(2)]ClO4 and {[}Cu(mb(2)en)(PPh3)(2)]BPh4: crystal structure of {[}Cu(mb(2)en)(2)]ClO4}}, type = {{Article}}, unique-id = {{ISI:000253265600016}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{1}}, volume = {{61}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2008}} }