%0 Journal Article %1 ISI:000251617600017 %A Amani, Vahid %A Safari, Nasser %A Khavasi, Hamid Reza %A Mirzaei, Peiman %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2007 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K 1, 10-phenanthroline; 2,2 `-bipyridine; chloride; crystal dimethyl structure} sulfoxide; {iron(III); %N 17 %P 4908-4914 %R 10.1016/j.poly.2007.06.038 %T Iron(III) mixed-ligand complexes: Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 1,10-phenanthroline, 2,2 `-bipyridine, chloride and dimethyl sulfoxide, Fe(phen)Cl-3(DMSO) and Fe(bipy)Cl-3(DMSO) %V 26 %X Treatment of Fe(bipy)Cl-4bipy center dot H (1) and Fe(phen)Cl-4phen center dot H (3) (where bipy is 2,2'-bipyridine and phen is 1,10-phenanthroline) with dimethyl sulfoxide in methanolic solution produced Fe(bipy)Cl-3(DMSO) (2) and Fe(phen)Cl-3(DMSO) (4) (where DMSO is dimethyl sulfoxide), respectively. The resulting complexes were characterized by elemental analysis, IR, UV-Vis and H-1 NMR spectroscopies and by the X-ray diffraction method. These complexes are high spin with a spin multiplicity of 6. (C) 2007 Elsevier Ltd. All rights reserved.

@article{ISI:000251617600017, abstract = {{Treatment of {[}Fe(bipy)Cl-4]{[}bipy center dot H] (1) and {[}Fe(phen)Cl-4]{[}phen center dot H] (3) (where bipy is 2,2'-bipyridine and phen is 1,10-phenanthroline) with dimethyl sulfoxide in methanolic solution produced {[}Fe(bipy)Cl-3(DMSO)] (2) and {[}Fe(phen)Cl-3(DMSO)] (4) (where DMSO is dimethyl sulfoxide), respectively. The resulting complexes were characterized by elemental analysis, IR, UV-Vis and H-1 NMR spectroscopies and by the X-ray diffraction method. These complexes are high spin with a spin multiplicity of 6. (C) 2007 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran. Amani, Vahid; Safari, Nasser; Khavasi, Hamid Reza; Mirzaei, Peiman, Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Amani, Vahid and Safari, Nasser and Khavasi, Hamid Reza and Mirzaei, Peiman}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/20873015a0e7623c253fb38bc32c06e12/hkhavasi}, cited-references = {{AMANI V, 2007, IN PRESS POLYHEDRON. Bachas LG, 1997, J CHEM SOC DALTON, P1571, DOI 10.1039/a608468k. BAKER J, 1975, J CHEM SOC DALTON, P530, DOI 10.1039/dt9750000530. Balzani V, 1996, CHEM REV, V96, P759, DOI 10.1021/cr941154y. Binnemans K, 2004, J MATER CHEM, V14, P191, DOI 10.1039/b311128h. Calderazzo F, 2002, INORG CHIM ACTA, V330, P136, DOI 10.1016/S0020-1693(01)00711-3. CHALK SJ, 1994, ANAL CHEM, V66, P660, DOI 10.1021/ac00077a013. Chow CS, 1997, CHEM REV, V97, P1489, DOI 10.1021/cr960415w. EVANS DF, 1959, J CHEM SOC, P2003, DOI 10.1039/jr9590002003. FIGGIS BN, 1983, AUST J CHEM, V36, P2043. 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Yan B, 2000, J CHIN CHEM SOC-TAIP, V47, P1211.}}, doc-delivery-number = {{240VZ}}, doi = {{10.1016/j.poly.2007.06.038}}, interhash = {c247302e71b7b53b6bb65a2321cfb118}, intrahash = {0873015a0e7623c253fb38bc32c06e12}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {1, 10-phenanthroline; 2,2 `-bipyridine; chloride; crystal dimethyl structure} sulfoxide; {iron(III);}, keywords-plus = {{TRANSITION-METAL-COMPLEXES; ELECTROCHEMICAL POLYMERIZATION; ALPHA,ALPHA-DIIMINE SYSTEM; X-RAY; LUMINESCENT; FILMS; RESONANCE; OXIDATION; PROPERTY}}, language = {{English}}, month = {{OCT 30}}, number = {{17}}, number-of-cited-references = {{43}}, pages = {{4908-4914}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{44}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Iron(III) mixed-ligand complexes: Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 1,10-phenanthroline, 2,2 `-bipyridine, chloride and dimethyl sulfoxide, {[}Fe(phen)Cl-3(DMSO)] and {[}Fe(bipy)Cl-3(DMSO)]}}, type = {{Article}}, unique-id = {{ISI:000251617600017}}, usage-count-last-180-days = {{2}}, usage-count-since-2013 = {{13}}, volume = {{26}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2007}} }