%0 Journal Article %1 AENM:AENM201701722 %A Chen, Tzu-Pei %A Lin, Chung-Wei %A Li, Shao-Sian %A Tsai, Yung-Han %A Wen, Cheng-Yen %A Lin, Wendy Jessica %A Hsiao, Fei-Man %A Chiu, Ya-Ping %A Tsukagoshi, Kazuhito %A Osada, Minoru %A Sasaki, Takayoshi %A Chen, Chun-Wei %D 2017 %J Advanced Energy Materials %K ETL new_material perovskite processing %P n/a--n/a %R 10.1002/aenm.201701722 %T Self-Assembly Atomic Stacking Transport Layer of 2D Layered Titania for Perovskite Solar Cells with Extended UV Stability %U http://dx.doi.org/10.1002/aenm.201701722 %X A novel atomic stacking transporting layer (ASTL) based on 2D atomic sheets of titania (Ti1−δO2) is demonstrated in organic–inorganic lead halide perovskite solar cells. The atomically thin ASTL of 2D titania, which is fabricated using a solution-processed self-assembly atomic layer-by-layer deposition technique, exhibits the unique features of high UV transparency and negligible (or very low) oxygen vacancies, making it a promising electron transporting material in the development of stable and high-performance perovskite solar cells. In particular, the solution-processable atomically thin ASTL of 2D titania atomic sheets shows superior inhibition of UV degradation of perovskite solar cell devices, compared to the conventional high-temperature sintered TiO2 counterpart, which usually causes the notorious instability of devices under UV irradiation. The discovery opens up a new dimension to utilize the 2D layered materials with a great variety of homostructrual or heterostructural atomic stacking architectures to be integrated with the fabrication of large-area photovoltaic or optoelectronic devices based on the solution processes.

@article{AENM:AENM201701722, abstract = {A novel atomic stacking transporting layer (ASTL) based on 2D atomic sheets of titania (Ti1−δO2) is demonstrated in organic–inorganic lead halide perovskite solar cells. The atomically thin ASTL of 2D titania, which is fabricated using a solution-processed self-assembly atomic layer-by-layer deposition technique, exhibits the unique features of high UV transparency and negligible (or very low) oxygen vacancies, making it a promising electron transporting material in the development of stable and high-performance perovskite solar cells. In particular, the solution-processable atomically thin ASTL of 2D titania atomic sheets shows superior inhibition of UV degradation of perovskite solar cell devices, compared to the conventional high-temperature sintered TiO2 counterpart, which usually causes the notorious instability of devices under UV irradiation. The discovery opens up a new dimension to utilize the 2D layered materials with a great variety of homostructrual or heterostructural atomic stacking architectures to be integrated with the fabrication of large-area photovoltaic or optoelectronic devices based on the solution processes.}, added-at = {2017-11-06T11:41:38.000+0100}, author = {Chen, Tzu-Pei and Lin, Chung-Wei and Li, Shao-Sian and Tsai, Yung-Han and Wen, Cheng-Yen and Lin, Wendy Jessica and Hsiao, Fei-Man and Chiu, Ya-Ping and Tsukagoshi, Kazuhito and Osada, Minoru and Sasaki, Takayoshi and Chen, Chun-Wei}, biburl = {https://www.bibsonomy.org/bibtex/2554db470753d3f8c076b6cafe7e1a2f2/bretschneider_m}, doi = {10.1002/aenm.201701722}, interhash = {264de9a4fae442f218dd94e05d7dd778}, intrahash = {554db470753d3f8c076b6cafe7e1a2f2}, issn = {1614-6840}, journal = {Advanced Energy Materials}, keywords = {ETL new_material perovskite processing}, pages = {n/a--n/a}, timestamp = {2017-11-06T11:42:39.000+0100}, title = {Self-Assembly Atomic Stacking Transport Layer of 2D Layered Titania for Perovskite Solar Cells with Extended UV Stability}, url = {http://dx.doi.org/10.1002/aenm.201701722}, year = 2017 }