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Direct determination of defect density of states in organic bulk heterojunction solar cells

, , and . Applied Physics Letters, (2016)
DOI: http://dx.doi.org/10.1063/1.4962827

Abstract

The measurement of the occupied trap density of states (DOS) is important for optimization of organic bulk heterojunction solar cells. We demonstrate a direct method for obtaining it from the trap related peak in capacitance-voltage characteristics under different levels of illumination, and its correlation with the dark current density-voltage characteristics. We use the method to measure the parameters of DOS, occupied trap distribution, and its temperature dependence for poly(3-hexathiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM) based solar cells. The total occupied trap concentration is approximately 7 × 1015 cm−3 with a standard deviation for a truncated Gaussian distribution varying between 32 and 44 meV in the temperature range of 310–270 K within a total Gaussian DOS with a standard deviation of 92 meV.

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Direct determination of defect density of states in organic bulk heterojunction solar cells

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