We report Boyle temperatures of 83 pure substances calculated using the Zeno (unit compressibility) line from standard or reference equations of state (EOS). We compare the results using different EOS and from correlations already published in the literature. The maximum absolute difference in the calculation of the Boyle temperature from different EOS is 15, 3, 24 and 63 K for hydrocarbons, gases, freons, and other substances, respectively. For alcohols, the difference in calculated Boyle temperatures is 300 K for methanol and 5 K for ethanol.
Beschreibung
ScienceDirect - Fluid Phase Equilibria : Boyle temperatures for pure substances
%0 Journal Article
%1 EstradaTorres2007148
%A Estrada-Torres, Raquel
%A Iglesias-Silva, Gustavo A.
%A Ramos-Estrada, Mariana
%A Hall, Kenneth R.
%D 2007
%J Fluid Phase Equilibria
%K 2007 Boyle equation-of-state
%N 2
%P 148 - 154
%R 10.1016/j.fluid.2007.06.004
%T Boyle temperatures for pure substances
%U http://dx.doi.org/10.1016/j.fluid.2007.06.004
%V 258
%X We report Boyle temperatures of 83 pure substances calculated using the Zeno (unit compressibility) line from standard or reference equations of state (EOS). We compare the results using different EOS and from correlations already published in the literature. The maximum absolute difference in the calculation of the Boyle temperature from different EOS is 15, 3, 24 and 63 K for hydrocarbons, gases, freons, and other substances, respectively. For alcohols, the difference in calculated Boyle temperatures is 300 K for methanol and 5 K for ethanol.
@article{EstradaTorres2007148,
abstract = {We report Boyle temperatures of 83 pure substances calculated using the Zeno (unit compressibility) line from standard or reference equations of state (EOS). We compare the results using different EOS and from correlations already published in the literature. The maximum absolute difference in the calculation of the Boyle temperature from different EOS is 15, 3, 24 and 63 K for hydrocarbons, gases, freons, and other substances, respectively. For alcohols, the difference in calculated Boyle temperatures is 300 K for methanol and 5 K for ethanol.},
added-at = {2011-05-24T15:34:54.000+0200},
author = {Estrada-Torres, Raquel and Iglesias-Silva, Gustavo A. and Ramos-Estrada, Mariana and Hall, Kenneth R.},
biburl = {https://www.bibsonomy.org/bibtex/27cb00be13a7c8bb7bdda8c93975b7e24/thorade},
description = {ScienceDirect - Fluid Phase Equilibria : Boyle temperatures for pure substances},
doi = {10.1016/j.fluid.2007.06.004},
interhash = {a69ca7b3880a6dd34bccdc43e58a95f9},
intrahash = {7cb00be13a7c8bb7bdda8c93975b7e24},
issn = {0378-3812},
journal = {Fluid Phase Equilibria},
keywords = {2007 Boyle equation-of-state},
number = 2,
pages = {148 - 154},
timestamp = {2011-05-24T15:34:54.000+0200},
title = {Boyle temperatures for pure substances},
url = {http://dx.doi.org/10.1016/j.fluid.2007.06.004},
volume = 258,
year = 2007
}