By including the theory of fluctuations in the axioms of thermodynamics it is shown that thermodynamic systems can be represented by Riemannian manifolds. Of special interest is the curvature of these manifolds which, for pure fluids, is associated with effective interparticle interaction strength by means of a general thermodynamic "interaction hypothesis." This interpretation of curvature appears to be consistent with hyperscaling and two-scale-factor universality. The Riemannian geometric model is a new attempt to extract information from the axioms of thermodynamics.
Description
Phys. Rev. A 20, 1608 (1979): Thermodynamics: A Riemannian geometric model
%0 Journal Article
%1 PhysRevA.20.1608
%A Ruppeiner, George
%D 1979
%I American Physical Society
%J Phys. Rev. A
%K 1979 mathematics molecular physics thermodynamic
%N 4
%P 1608--1613
%R 10.1103/PhysRevA.20.1608
%T Thermodynamics: A Riemannian geometric model
%U http://dx.doi.org/10.1103/PhysRevA.20.1608
%V 20
%X By including the theory of fluctuations in the axioms of thermodynamics it is shown that thermodynamic systems can be represented by Riemannian manifolds. Of special interest is the curvature of these manifolds which, for pure fluids, is associated with effective interparticle interaction strength by means of a general thermodynamic "interaction hypothesis." This interpretation of curvature appears to be consistent with hyperscaling and two-scale-factor universality. The Riemannian geometric model is a new attempt to extract information from the axioms of thermodynamics.
@article{PhysRevA.20.1608,
abstract = {By including the theory of fluctuations in the axioms of thermodynamics it is shown that thermodynamic systems can be represented by Riemannian manifolds. Of special interest is the curvature of these manifolds which, for pure fluids, is associated with effective interparticle interaction strength by means of a general thermodynamic "interaction hypothesis." This interpretation of curvature appears to be consistent with hyperscaling and two-scale-factor universality. The Riemannian geometric model is a new attempt to extract information from the axioms of thermodynamics.},
added-at = {2013-01-23T14:48:25.000+0100},
author = {Ruppeiner, George},
biburl = {https://www.bibsonomy.org/bibtex/2d764865faa79793ddfc95b862c0e3275/thorade},
description = {Phys. Rev. A 20, 1608 (1979): Thermodynamics: A Riemannian geometric model},
doi = {10.1103/PhysRevA.20.1608},
interhash = {2cc4cfabbc7ddbe9bbd6ae92d64177f4},
intrahash = {d764865faa79793ddfc95b862c0e3275},
journal = {Phys. Rev. A},
keywords = {1979 mathematics molecular physics thermodynamic},
month = oct,
number = 4,
pages = {1608--1613},
publisher = {American Physical Society},
timestamp = {2013-01-28T17:04:02.000+0100},
title = {Thermodynamics: A Riemannian geometric model},
url = {http://dx.doi.org/10.1103/PhysRevA.20.1608},
volume = 20,
year = 1979
}