%0 Journal Article %1 ISI:000248633900059 %A Sabounchei, Seyyed Javad %A Jodaian, Vida %A Khavasi, Hamid Reza %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2007 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K X-ray complexes; crystal halide mercury(II) structure; triphenylphosphine} ylide; {phosphorus %N 12 %P 2845-2850 %R 10.1016/j.poly.2007.01.053 %T Synthesis, spectroscopic and X-ray structural studies of mercury(II) halide complexes of 4-methoxybenzoylmethylenetriphenylphosphorane %V 26 %X The reactions of the title ylide \(C6H5)(3)PCHCOC6H4OCH3)\ (MBPPY) with mercury(II) chloride and mercury(II) bromide in equimolar ratios using methanol as the solvent produces crystals of (MBPPY) (.) HgBr2(2) (1) and (MBPPY) (.) HgBr2(2) (2), respectively. Single crystal X-ray analyses reveal the presence of centrosymmetric dimeric structures containing the ylide and HgX2 (X = Cl or Br) in both cases. The IR and NMR data of the product (MBPPY) (.) HgI2(2) (3), formed by the reaction of mercury(II) iodide with the same ylide, are similar to those of 1 and 2. Analytical data indicate a 1:1 stoichiometry between the ylide and Hg(ll) halide in each of the three products. (C) 2007 Elsevier Ltd. All rights reserved.

@article{ISI:000248633900059, abstract = {{The reactions of the title ylide \{(C6H5)(3)PCHCOC6H4OCH3)\} (MBPPY) with mercury(II) chloride and mercury(II) bromide in equimolar ratios using methanol as the solvent produces crystals of {[}(MBPPY) (.) HgBr2](2) (1) and {[}(MBPPY) (.) HgBr2](2) (2), respectively. Single crystal X-ray analyses reveal the presence of centrosymmetric dimeric structures containing the ylide and HgX2 (X = Cl or Br) in both cases. The IR and NMR data of the product {[}(MBPPY) (.) HgI2](2) (3), formed by the reaction of mercury(II) iodide with the same ylide, are similar to those of 1 and 2. Analytical data indicate a 1:1 stoichiometry between the ylide and Hg(ll) halide in each of the three products. (C) 2007 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Sabounchei, SJ (Reprint Author), Bu Ali Sina Univ, Fac Chem, Hamadan, Iran. Bu Ali Sina Univ, Fac Chem, Hamadan, Iran. Shahid Beheshti Univ, Dept Chem, Tehran 19839, Iran.}}, author = {Sabounchei, Seyyed Javad and Jodaian, Vida and Khavasi, Hamid Reza}, author-email = {{jsabounchei@yahoo.co.uk}}, biburl = {https://www.bibsonomy.org/bibtex/2d35548466a2ed69e9ff9bbaf8e4b9306/hkhavasi}, cited-references = {{ALBANESE JA, 1990, INORG CHEM, V29, P2209, DOI 10.1021/ic00337a007. ALBINATI A, 1984, INORG CHIM ACTA, V38, P221. BAENZIGER NC, 1978, ACTA CRYSTALLOGR B, V34, P2300, DOI 10.1107/S0567740878007967. Bell NA, 2000, POLYHEDRON, V19, P1719, DOI 10.1016/S0277-5387(00)00451-4. Belluco U, 1996, INORG CHIM ACTA, V252, P355, DOI 10.1016/S0020-1693(96)05358-3. Bent HA, 1961, CHEM REV, V61, P75, DOI {[}10.1021/cr60211a005, DOI 10.1021/CR60211A005]. BUCKLE J, 1973, J ORGANOMET CHEM, V49, pC17, DOI 10.1016/S0022-328X(00)84920-7. BUCKLE J, 1972, J CHEM SOC CHEM COMM, P1104, DOI 10.1039/c39720001104. Burmeister JL, 1973, SYNTH REACT INORG M, V3, P339, DOI 10.1080/0094 5717308057280. Cobridge D. E. C, 1995, PHOSPHORUS OUTLINE C. FACCHIN G, 1987, J CHEM SOC DALTON, P1381, DOI 10.1039/dt9870001381. Gordon A. J., 1972, CHEM COMPANION, P438. HOLY NL, 1976, J AM CHEM SOC, V98, P7823, DOI 10.1021/ja00440a062. HUBEEY JE, 1978, INORGANIC CHEM PRINC, P233. ILLINGSWORTH ML, 1983, ORGANOMETALLICS, V2, P1364, DOI 10.1021/om50004a019. Kalyanasundari B, 1999, B CHEM SOC JPN, V72, P33. KALYANASUNDARI M, 1994, ACTA CRYSTALLOGR C, V50, P1738, DOI 10.1107/S0108270194001137. KALYANASUNDARI M, 1995, J ORGANOMET CHEM, V491, P103, DOI 10.1016/0022-328X(94)05217-Y. KAWAFUNE I, 1983, INORG CHIM A-ARTICLE, V70, P1, DOI 10.1016/S0020-1693(00)82769-3. Kolodiazhnyi O. I., 1997, RUSS CHEM REV, V66, P225, DOI DOI 10.1070/RC1997V066N03ABEH000232. Laavanya P, 2001, CHEM COMMUN, P1660, DOI 10.1039/b104082k. LUTTKE W, 1965, ANGEW CHEM INT EDIT, V4, P875, DOI 10.1002/anie.196508752. NISHIYAMA H, 1975, J ORGANOMET CHEM, V87, P129, DOI 10.1016/S0022-328X(00)80349-6. ONISHI M, 1982, POLYHEDRON, V1, P539, DOI 10.1016/S0277-5387(00)81609-5. Puke C, 1998, J AM CHEM SOC, V120, P4863, DOI 10.1021/ja9720669. RAMIREZ F, 1957, J ORG CHEM, V22, P41, DOI 10.1021/jo01352a010. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. Shen YC, 1998, ACCOUNTS CHEM RES, V31, P584, DOI 10.1021/ar970060i. TEAGLE JA, 1986, INORG CHIM ACTA, V118, P65, DOI 10.1016/S0020-1693(00)86408-7. USON R, 1985, J ORGANOMET CHEM, V290, P125, DOI 10.1016/0022-328X(85)80154-6. VICENTE J, 1989, J ORGANOMET CHEM, V364, P407, DOI 10.1016/0022-328X(89)87150-5. VICENTE J, 1987, J ORGANOMET CHEM, V331, P409, DOI 10.1016/0022-328X(87)80012-8. VICENTE J, 1991, J CHEM SOC DALTON, P2579, DOI 10.1039/dt9910002579.}}, doc-delivery-number = {{198ND}}, doi = {{10.1016/j.poly.2007.01.053}}, interhash = {3c758672aa20dbae92d1c641f2de08ae}, intrahash = {d35548466a2ed69e9ff9bbaf8e4b9306}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {X-ray complexes; crystal halide mercury(II) structure; triphenylphosphine} ylide; {phosphorus}, keywords-plus = {{UNPRECEDENTED O-COORDINATION; CARBONYL-STABILIZED YLIDES; MOLECULAR-STRUCTURE; SILVER(I) COMPLEXES; PHOSPHORUS YLIDES; CRYSTAL-STRUCTURE; BENZOYLMETHYLENETRIPHENYLPHOSPHORANE; PALLADIUM(II); DERIVATIVES; LIGANDS}}, language = {{English}}, month = {{JUL 23}}, number = {{12}}, number-of-cited-references = {{33}}, pages = {{2845-2850}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{28}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, spectroscopic and X-ray structural studies of mercury(II) halide complexes of 4-methoxybenzoylmethylenetriphenylphosphorane}}, type = {{Article}}, unique-id = {{ISI:000248633900059}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{2}}, volume = {{26}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2007}} }