%0 Journal Article %1 ANDP:ANDP19273892002 %A Born, M. %A Oppenheimer, R. %D 1927 %I WILEY-VCH Verlag %J Annalen der Physik %K energy mechanics perturbation physics potential quantum surface theory %N 20 %P 457--484 %R 10.1002/andp.19273892002 %T Zur Quantentheorie der Molekeln %U http://dx.doi.org/10.1002/andp.19273892002 %V 389 %X It will be shown that the familiar components of the terms of a molecule; the energy of electronic motion, of the nuclear vibration and of the rotation, correspond systematically to the terms of a power series in the fourth root of the ratio of electron mass to (average) nuclear mass. The treatment yields among other things an equation for the rotation, which represents a generalization of the treatment of Kramers and Pauli (top with built-in fly-wheel). Furthermore, there appears a justification of the considerations of Franck and Condon on the intensity of band lines. The relationships are illustrated for the diatomic molecule.

@article{ANDP:ANDP19273892002, abstract = {It will be shown that the familiar components of the terms of a molecule; the energy of electronic motion, of the nuclear vibration and of the rotation, correspond systematically to the terms of a power series in the fourth root of the ratio of electron mass to (average) nuclear mass. The treatment yields among other things an equation for the rotation, which represents a generalization of the treatment of Kramers and Pauli (top with built-in fly-wheel). Furthermore, there appears a justification of the considerations of Franck and Condon on the intensity of band lines. The relationships are illustrated for the diatomic molecule. }, added-at = {2013-06-16T05:50:45.000+0200}, author = {Born, M. and Oppenheimer, R.}, biburl = {https://www.bibsonomy.org/bibtex/2595e9d1cacfd4b3497f5612948fd4dcc/drmatusek}, doi = {10.1002/andp.19273892002}, interhash = {5cb87902f1089dc78089072508b02d9e}, intrahash = {595e9d1cacfd4b3497f5612948fd4dcc}, issn = {1521-3889}, journal = {Annalen der Physik}, keywords = {energy mechanics perturbation physics potential quantum surface theory}, note = {PDF of an english translation by S.M. Blinder is available.}, number = 20, pages = {457--484}, publisher = {WILEY-VCH Verlag}, timestamp = {2013-10-04T18:02:15.000+0200}, title = {Zur Quantentheorie der Molekeln}, url = {http://dx.doi.org/10.1002/andp.19273892002}, volume = 389, year = 1927 }