%0 Journal Article %1 citeulike:10319711 %A Ward, C. A. %A Balakrishnan, A. %A Hooper, F. C. %D 1970 %I ASME %J Journal of Basic Engineering %K 82c26-dynamic-nonequilibrium-phase-transitions %N 4 %P 695--701 %R 10.1115/1.3425107 %T On the Thermodynamics of Nucleation in Weak Gas-Liquid Solutions %U http://dx.doi.org/10.1115/1.3425107 %V 92 %X Gas-vapor nucleation in liquid solutions is considered. It is shown that for nucleation to occur in a multicomponent solution a nucleus must be created of at least a certain radius. Consideration is then restricted to weak solutions of gas dissolved in liquids with the gas allowed to behave nonideally. A generalized Kelvin equation is derived which relates the partial pressure of the solvent vapor inside a nucleus to the properties of the surrounding solution. It is shown how, for a given temperature, the pressure at which nucleation occurs in a gas-liquid solution is increased as the gas concentration is increased.

@article{citeulike:10319711, abstract = {{Gas-vapor nucleation in liquid solutions is considered. It is shown that for nucleation to occur in a multicomponent solution a nucleus must be created of at least a certain radius. Consideration is then restricted to weak solutions of gas dissolved in liquids with the gas allowed to behave nonideally. A generalized Kelvin equation is derived which relates the partial pressure of the solvent vapor inside a nucleus to the properties of the surrounding solution. It is shown how, for a given temperature, the pressure at which nucleation occurs in a gas-liquid solution is increased as the gas concentration is increased.}}, added-at = {2017-06-29T07:13:07.000+0200}, author = {Ward, C. A. and Balakrishnan, A. and Hooper, F. C.}, biburl = {https://www.bibsonomy.org/bibtex/20401816c716a76b39b4f311da45c7285/gdmcbain}, citeulike-article-id = {10319711}, citeulike-attachment-1 = {ward_70_on.pdf; /pdf/user/gdmcbain/article/10319711/747318/ward_70_on.pdf; 463d029c3880274a1ff5e2ef9f20034647ba1a84}, citeulike-linkout-0 = {http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal\&id=JBAEAI000092000004000695000001\&idtype=cvips\&gifs=yes}, citeulike-linkout-1 = {http://link.aip.org/link/?JBE/92/695}, citeulike-linkout-2 = {http://dx.doi.org/10.1115/1.3425107}, comment = {(private-note)circulated by sam 2012-02-07 during a discussion on the effect of dissolved gas}, doi = {10.1115/1.3425107}, file = {ward_70_on.pdf}, interhash = {a69f878e95aea61414ab9afd248f6e91}, intrahash = {0401816c716a76b39b4f311da45c7285}, journal = {Journal of Basic Engineering}, keywords = {82c26-dynamic-nonequilibrium-phase-transitions}, number = 4, pages = {695--701}, posted-at = {2012-02-07 02:22:46}, priority = {2}, publisher = {ASME}, timestamp = {2017-06-29T07:13:07.000+0200}, title = {{On the Thermodynamics of Nucleation in Weak Gas-Liquid Solutions}}, url = {http://dx.doi.org/10.1115/1.3425107}, volume = 92, year = 1970 }