Abstract
A versatile algorithm is proposed for solving vapour--liquid equilibrium problems. It has been prepared so that the search procedure is generally applicable with any analytical equation of state and any kind of data. Special attention is paid to the applicability of the method in critical and high-pressure regions. Derivatives of the quantities describing the state of the system can be obtained for any equilibrium state as soon as equilibrium is determined. Results are reported for computing based on the use of a modified Redlich--Kwong equation of state.
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