%0 Journal Article %1 WOS:000507334200001 %A de Pereira, Mauricio Sousa %A de Sousa Lima, Francisco Anderson %A de Almeida, Rodrigo Queiros %A da Silva Martins, Juliana Luiza %A Bagnis, Diego %A Barros, Eduardo Bede %A Sombra, Antonio Sergio Bezerra %A de Vasconcelos, Igor Frota %C LABORATORIA DE MATERIAIS VITREOS, CAIXA POSTAL 676, SAO CARLOS, 13565-905SP, BRAZIL %D 2019 %I UNIV FED SAO CARLOS, DEPT ENGENHARIA MATERIALS %J MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS %K CoFe2O4 P3HT:PCBM and cells; conversion efficiency; films; lifetime} nanoparticles; power solar stability {Organic %N 6 %R 10.1590/1980-5373-MR-2019-0417 %T Flexible, Large-Area Organic Solar Cells With Improved Performance Through Incorporation of CoFe2O4 Nanoparticles in the Active Layer %V 22 %X Cobalt ferrite (CoFe2O4) nanoparticles (NPs), with an average diameter of about 4-10 nm, were produced by the proteic sol-gel method and successfully doped into the active layer of poly(3-hexylthiophene-2,5-diyl) (P3HT): 6,6-phenyl-C61-butyric acid methyl ester (PCBM) organic solar cells. Pristine and CoFe2O4 NPs-doped blends of P3HT:PCBM were dispersed in a mixture of o-xylene:tetralin (1 mg/mL) based non-halogenated solvents and deposited via a semi-industrial blade coating process on flexible substrates to fabricate large area (0.55 cm(2)), flexible organic solar cells with inverted configuration. The main focus of this study aims to assess the influence of NPs on the efficiency, stability and lifetime of the produced devices. From the photovoltaic parameters it was observed that the optimization of the bulk-heterojunction through the incorporation of CoFe2O4 NPs resulted in increased short-circuit current density. As a result, the power conversion efficiency of doped devices increased by 10 % when compared with the undoped reference devices. Tests of lifetime and stability were performed using International Summit on OPV Stability (ISOS) protocols ISOS-D-3, ISOS-0-1 and ISOS-L-1. For the duration of the tests (1200 h), the results showed that doped cells presented performances at least comparable with those of reference cells.

@article{WOS:000507334200001, abstract = {Cobalt ferrite (CoFe2O4) nanoparticles (NPs), with an average diameter of about 4-10 nm, were produced by the proteic sol-gel method and successfully doped into the active layer of poly(3-hexylthiophene-2,5-diyl) (P3HT): [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) organic solar cells. Pristine and CoFe2O4 NPs-doped blends of P3HT:PCBM were dispersed in a mixture of o-xylene:tetralin (1 mg/mL) based non-halogenated solvents and deposited via a semi-industrial blade coating process on flexible substrates to fabricate large area (0.55 cm(2)), flexible organic solar cells with inverted configuration. The main focus of this study aims to assess the influence of NPs on the efficiency, stability and lifetime of the produced devices. From the photovoltaic parameters it was observed that the optimization of the bulk-heterojunction through the incorporation of CoFe2O4 NPs resulted in increased short-circuit current density. As a result, the power conversion efficiency of doped devices increased by 10 % when compared with the undoped reference devices. Tests of lifetime and stability were performed using International Summit on OPV Stability (ISOS) protocols ISOS-D-3, ISOS-0-1 and ISOS-L-1. For the duration of the tests (1200 h), the results showed that doped cells presented performances at least comparable with those of reference cells.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {LABORATORIA DE MATERIAIS VITREOS, CAIXA POSTAL 676, SAO CARLOS, 13565-905SP, BRAZIL}, author = {de Pereira, Mauricio Sousa and de Sousa Lima, Francisco Anderson and de Almeida, Rodrigo Queiros and da Silva Martins, Juliana Luiza and Bagnis, Diego and Barros, Eduardo Bede and Sombra, Antonio Sergio Bezerra and de Vasconcelos, Igor Frota}, biburl = {https://www.bibsonomy.org/bibtex/2dbe8672809791c6823d8ef5805b01e50/ppgfis_ufc_br}, doi = {10.1590/1980-5373-MR-2019-0417}, interhash = {e9b9b922562d58358df9b2aecb689171}, intrahash = {dbe8672809791c6823d8ef5805b01e50}, issn = {1516-1439}, journal = {MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS}, keywords = {CoFe2O4 P3HT:PCBM and cells; conversion efficiency; films; lifetime} nanoparticles; power solar stability {Organic}, number = 6, publisher = {UNIV FED SAO CARLOS, DEPT ENGENHARIA MATERIALS}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Flexible, Large-Area Organic Solar Cells With Improved Performance Through Incorporation of CoFe2O4 Nanoparticles in the Active Layer}, tppubtype = {article}, volume = 22, year = 2019 }