%0 Journal Article %1 Albaladejo:2003p3362 %A Albaladejo, J %A Notario, A %A Cuevas, CA %A Jimenez, E %A Cabanas, B %A Martinez, E %D 2003 %J Atmospheric Environment %K Air Alkanes, Atmospheric Atoms, Chemistry, Chlorine Constants, Et-Al, Gas-Phase Ketones, Laser Laser-Photolysis Mechanisms, Oh Photolysis, Radical Radicals, Rate Reaction, Reactions, Technique, Tropospheric %N 4 %P 455--463 %T Gas-phase chemistry of atmospheric Cl atoms: a PLP-RF kinetic study with a series of ketones %V 37 %X The pulsed laser photolysis-resonance fluorescence technique (PLP-RF) has been used to determine the absolute rate coefficients for the gas-phase reactions of Cl atoms with a series of ketones at room temperature (298 K). The rate coefficients obtained (in units of cm(3) Molecule(-1) s(-1)) are: 2-butanone (3.30 +/- 0.20) x 10(-11), 2,3-butadione (4.92 +/- 0.44) x 10(-13), 2-pentanone (4.57 +/- 0.28) x 10(-11), 3-pentanone (4.50 +/- 0.32) x 10(-11), 2-hexanone (6.54 +/- 0.58) x 10(-11), 3-hexanone (6.69 +/- 0.62) x 10(-11) and cyclohexanone (6.75 +/- 0.52) x 10(-11). The measured values were independent of pressure over the range 20-200 Torr. These rate coefficients were compared with previous studies carried out by different techniques, when data were available. Results and atmospheric implications are discussed and compared with the reactivity with OH radicals. (C) 2002 Elsevier Science Ltd. All rights reserved.

@article{Albaladejo:2003p3362, abstract = {The pulsed laser photolysis-resonance fluorescence technique (PLP-RF) has been used to determine the absolute rate coefficients for the gas-phase reactions of Cl atoms with a series of ketones at room temperature (298 K). The rate coefficients obtained (in units of cm(3) Molecule(-1) s(-1)) are: 2-butanone (3.30 +/- 0.20) x 10(-11), 2,3-butadione (4.92 +/- 0.44) x 10(-13), 2-pentanone (4.57 +/- 0.28) x 10(-11), 3-pentanone (4.50 +/- 0.32) x 10(-11), 2-hexanone (6.54 +/- 0.58) x 10(-11), 3-hexanone (6.69 +/- 0.62) x 10(-11) and cyclohexanone (6.75 +/- 0.52) x 10(-11). The measured values were independent of pressure over the range 20-200 Torr. These rate coefficients were compared with previous studies carried out by different techniques, when data were available. Results and atmospheric implications are discussed and compared with the reactivity with OH radicals. (C) 2002 Elsevier Science Ltd. All rights reserved.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Univ Castilla La Mancha, Fac Ciencias Quim, Dept Quim Fis, E-13071 Ciudad Real, Spain}, author = {Albaladejo, J and Notario, A and Cuevas, CA and Jimenez, E and Cabanas, B and Martinez, E}, biburl = {https://www.bibsonomy.org/bibtex/2a9e68dc50905837fca3bfc7d57cbc3b0/gsmith}, date-added = {2010-05-04 15:13:17 -0400}, date-modified = {2010-05-04 15:13:17 -0400}, interhash = {f1b3257654964641e388e822ca11cf48}, intrahash = {a9e68dc50905837fca3bfc7d57cbc3b0}, journal = {Atmospheric Environment}, keywords = {Air Alkanes, Atmospheric Atoms, Chemistry, Chlorine Constants, Et-Al, Gas-Phase Ketones, Laser Laser-Photolysis Mechanisms, Oh Photolysis, Radical Radicals, Rate Reaction, Reactions, Technique, Tropospheric}, language = {English}, month = Jan, number = 4, pages = {455--463}, pmid = {000180675000002}, rating = {0}, timestamp = {2010-06-22T19:39:12.000+0200}, title = {Gas-phase chemistry of atmospheric Cl atoms: a PLP-RF kinetic study with a series of ketones}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3362}, volume = 37, year = 2003 }