This document defines an XML syntax for RDF called RDF/XML in terms of Namespaces in XML, the XML Information Set and XML Base. The formal grammar for the syntax is annotated with actions generating triples of the RDF graph as defined in RDF Concepts and Abstract Syntax.
Is the RDF model an entity-relationship mode? Yes and no. It is great as a basis for ER-modelling, but because RDF is used for other things as well, RDF is more general. RDF is a model of entities (nodes) and relationships.