%0 Journal Article %1 ISI:000291860700002 %A Ahmadi, Raziyeh Arab %A Safari, Nasser %A Khavasi, Hamid Reza %A Amani, Saeid %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2011 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K Crystal Magnetic cobalt(II); cobalt(II)} complexes; moment of structure {Cobalt(II) %N 12 %P 2056-2065 %R 10.1080/00958972.2011.587877 %T Four new Co(II) complexes with 2-amino-4-methylpyridine, 2-amino-3-methylpyridine, or 2-amino-5-chloropyridine: synthesis, spectroscopy, magnetic properties, and crystal structure %V 64 %X Solid-state structures for a series of Co(L)(2)X(2) complexes are assigned on the basis of magnetic moments, FTIR spectra, electronic spectra properties (L = 2-amino-4-methylpyridine, 2-amino-3- methylpyridine, or 2-amino-5-chloropyridine; X chloride or acetate). All complexes were prepared in one-step syntheses. The crystal structure of 2-amino-4-methylpyridine with cobalt(II) chloride Co(L)(2)(Cl)(2) was solved at room temperature. This compound consists of mononuclear units consisting of two ligands linked to cobalt via the pyridine. The complex crystallizes in the orthorhombic system, space group Pcan with z = 8. UV-Vis spectra show five absorption bands, attributed to d-d transitions of cobalt, ligand -> metal charge transfer, and pi -> pi* or n -> pi* transitions of ligand. FTIR spectra show CoL(2)X(2) vibrations at 550-300 cm(-1). The compounds show room temperature magnetic moments of 4.58-5.29 B.M., indicating high-spin cobalt(II).

@article{ISI:000291860700002, abstract = {{Solid-state structures for a series of {[}Co(L)(2)X(2)] complexes are assigned on the basis of magnetic moments, FTIR spectra, electronic spectra properties (L = 2-amino-4-methylpyridine, 2-amino-3- methylpyridine, or 2-amino-5-chloropyridine; X chloride or acetate). All complexes were prepared in one-step syntheses. The crystal structure of 2-amino-4-methylpyridine with cobalt(II) chloride {[}Co(L)(2)(Cl)(2)] was solved at room temperature. This compound consists of mononuclear units consisting of two ligands linked to cobalt via the pyridine. The complex crystallizes in the orthorhombic system, space group Pcan with z = 8. UV-Vis spectra show five absorption bands, attributed to d-d transitions of cobalt, ligand -> metal charge transfer, and pi -> pi{*} or n -> pi{*} transitions of ligand. FTIR spectra show CoL(2)X(2) vibrations at 550-300 cm(-1). The compounds show room temperature magnetic moments of 4.58-5.29 B.M., indicating high-spin cobalt(II).}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Amani, S (Reprint Author), Arak Univ, Dept Chem, Dr Beheshti Ave, Arak 3815688349, Iran. Ahmadi, Raziyeh Arab; Amani, Saeid, Arak Univ, Dept Chem, Arak 3815688349, Iran. Safari, Nasser; Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Ahmadi, Raziyeh Arab and Safari, Nasser and Khavasi, Hamid Reza and Amani, Saeid}, author-email = {{s-amani@araku.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2fb58345da505558870b89529eaa9800a/hkhavasi}, cited-references = {{Amani S., 1999, TRANSIT METAL CHEM, V24, P104. COHEN N, 1995, J CLIN INVEST, V95, P2501, DOI 10.1172/JCI117951. Conarmond J., 1982, J AM CHEM SOC, V104, P6330. Crans DC, 2000, J INORG BIOCHEM, V80, P123, DOI 10.1016/S0162-0134(00)00048-9. 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Zharnikova MA, 2002, RUSS J GEN CHEM+, V72, P131, DOI 10.1023/A:1015370001651.}}, doc-delivery-number = {{780MH}}, doi = {{10.1080/00958972.2011.587877}}, funding-acknowledgement = {{Research Council of Arak University}}, funding-text = {{The authors thank the Research Council of Arak University for financial support of this research.}}, interhash = {07c80eb362d07bfe2d96c847253c1fd2}, intrahash = {fb58345da505558870b89529eaa9800a}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {Crystal Magnetic cobalt(II); cobalt(II)} complexes; moment of structure {Cobalt(II)}, keywords-plus = {{INSULIN-LIKE PROPERTIES; SINGLE-CHAIN MAGNETS; COPPER(II) COMPLEXES; PARAMAGNETIC SUSCEPTIBILITY; COBALT(II); CHEMISTRY; LIGAND; SOLVENTS}}, language = {{English}}, number = {{12}}, number-of-cited-references = {{54}}, pages = {{2056-2065}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{1}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Four new Co(II) complexes with 2-amino-4-methylpyridine, 2-amino-3-methylpyridine, or 2-amino-5-chloropyridine: synthesis, spectroscopy, magnetic properties, and crystal structure}}, type = {{Article}}, unique-id = {{ISI:000291860700002}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{9}}, volume = {{64}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2011}} }