%0 Journal Article %1 C0JM00617C %A Park, Min-Sik %A Lee, Jong-Won %A Choi, Wonchang %A Im, Dongmin %A Doo, Seok-Gwang %A Park, Kyu-Sung %D 2010 %I The Royal Society of Chemistry %J J. Mater. Chem. %K aempl %N 34 %P 7208-7213 %R 10.1039/C0JM00617C %T On the surface modifications of high-voltage oxide cathodes for lithium-ion batteries: new insight and significant safety improvement %U http://dx.doi.org/10.1039/C0JM00617C %V 20 %X A layered oxide solid solution of LiMeO2 and Li2MnO3 (Me = Ni, Co, Fe, etc.), represented by the general formula LiLi1-x-yMexMnyO2, is being considered a promising cathode for advanced lithium-ion batteries owing to its high capacity. Here, the surface of high-voltage oxide cathode, specifically LiLi0.167Ni0.233Co0.100Mn0.467Mo0.033O2, is modified with Al2O3 and AlPO4 to address critical issues relating to safety and stability during cycling. Using in situ measurement of internal cell pressure, we demonstrate that the oxygen gas evolution upon high voltage charging is serious enough to raise a safety issue in practical batteries, but the problem can be greatly mitigated by surface modification. Furthermore, surface modification effectively prevents transition metal ions from leaching out of the electrode during cycling at elevated temperatures. The in-depth structural and electrochemical analyses indicate that in addition to the coated Al2O3 and AlPO4 species, Al3+ ions incorporated into the transition metal layers modify the surface structure and play a crucial role in improving safety and stability. Our experimental findings provide a direction to future developments of high capacity electrodes and batteries that are tolerant to high-voltage charging and high-temperature environments.

@article{C0JM00617C, abstract = {A layered oxide solid solution of LiMeO2 and Li2MnO3 (Me = Ni{,} Co{,} Fe{,} etc.){,} represented by the general formula Li[Li1-x-yMexMny]O2{,} is being considered a promising cathode for advanced lithium-ion batteries owing to its high capacity. Here{,} the surface of high-voltage oxide cathode{,} specifically Li[Li0.167Ni0.233Co0.100Mn0.467Mo0.033]O2{,} is modified with Al2O3 and AlPO4 to address critical issues relating to safety and stability during cycling. Using in situ measurement of internal cell pressure{,} we demonstrate that the oxygen gas evolution upon high voltage charging is serious enough to raise a safety issue in practical batteries{,} but the problem can be greatly mitigated by surface modification. Furthermore{,} surface modification effectively prevents transition metal ions from leaching out of the electrode during cycling at elevated temperatures. The in-depth structural and electrochemical analyses indicate that in addition to the coated Al2O3 and AlPO4 species{,} Al3+ ions incorporated into the transition metal layers modify the surface structure and play a crucial role in improving safety and stability. Our experimental findings provide a direction to future developments of high capacity electrodes and batteries that are tolerant to high-voltage charging and high-temperature environments.}, added-at = {2015-10-08T06:28:18.000+0200}, author = {Park, Min-Sik and Lee, Jong-Won and Choi, Wonchang and Im, Dongmin and Doo, Seok-Gwang and Park, Kyu-Sung}, biburl = {https://www.bibsonomy.org/bibtex/2aaa239441011c502022046fc219681ae/l1th1um}, description = {On the surface modifications of high-voltage oxide cathodes for lithium-ion batteries: new insight and significant safety improvement - Journal of Materials Chemistry (RSC Publishing)}, doi = {10.1039/C0JM00617C}, interhash = {3ec626ee9a828156d5b8f2d0ccbda95a}, intrahash = {aaa239441011c502022046fc219681ae}, journal = {J. Mater. Chem.}, keywords = {aempl}, number = 34, pages = {7208-7213}, publisher = {The Royal Society of Chemistry}, timestamp = {2015-10-08T06:28:18.000+0200}, title = {On the surface modifications of high-voltage oxide cathodes for lithium-ion batteries: new insight and significant safety improvement}, url = {http://dx.doi.org/10.1039/C0JM00617C}, volume = 20, year = 2010 }