%0 Journal Article %1 Chew:1998p3386 %A Chew, AA %A Atkinson, R %A ASCHMANN, SM %D 1998 %J Journal of the Chemical Society-Faraday Transactions %K Chemistry Constants, Detection, Ftir, Lif N2O5, Nitrate Organic-Compounds, Products, Radicals, Rate Temperature, %N 8 %P 1083--1089 %T Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes %U http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reactions+of+NO3+radicals+with+a+series+of+alcohols,+glycol+ethers,+ethers+and+chloroalkenes&ie=UTF-8&oe=UTF-8 %V 94 %X Using a relative rate method, rate constants have been measured for the gas-phase reactions of the NO3 radical with methacrolein, a series of ethers, glycol ethers, alcohols and chloroalkenes at 298 +/- 2 K and atmospheric pressure of air. The rate constants determined tin units of 10(-16) cm(3) molecule(-1) s(-1)) were: methacrolein, 33 +/- 10; diethyl ether, 31 +/- 10; di-n-propyl ether, 49 +/- 16; diisopropyl ether, 40 +/- 13; ethyl tert-butyl ether, 45 +/- 14; 1-methoxypropan-2-ol, less than or equal to 15 +/- 5; 2-butoxyethanol, less than or equal to 31 +/- 11; propan-1-ol, less than or equal to 21 +/- 8; propan-2-ol, less than or equal to 17 +/- 6; butan-1-ol, less than or equal to 27 +/- 10; butan-2-ol, less than or equal to 25 +/- 8; heptan-4-ol, less than or equal to 60 +/- 20; cis-1,2-dichloroethene, 1.3 +/- 1.3; 1,1-dichloroethene, 18(-6)(+9); trichloroethene, 3.6(-1.5)(+2.0); tetrachloroethene, <1.8; and 3-chloropropene, 5.8(-2.0)(+3.0). Carbonyl products of the alcohol reactions arising after H-atom abstraction at the carbon atom to which the -OH group is attached were observed, and rate constants for this reaction pathway obtained. Significant discrepancies with the literature concern propan-2-ol, ethyl tert-butyl ether and 3-chloropropene, with our relative rate constants for these compounds being factors of ca. 2, ca. 2, and ca. 8 lower, respectively, than previously reported absolute rate constant determinations.

@article{Chew:1998p3386, abstract = {Using a relative rate method, rate constants have been measured for the gas-phase reactions of the NO3 radical with methacrolein, a series of ethers, glycol ethers, alcohols and chloroalkenes at 298 +/- 2 K and atmospheric pressure of air. The rate constants determined tin units of 10(-16) cm(3) molecule(-1) s(-1)) were: methacrolein, 33 +/- 10; diethyl ether, 31 +/- 10; di-n-propyl ether, 49 +/- 16; diisopropyl ether, 40 +/- 13; ethyl tert-butyl ether, 45 +/- 14; 1-methoxypropan-2-ol, less than or equal to 15 +/- 5; 2-butoxyethanol, less than or equal to 31 +/- 11; propan-1-ol, less than or equal to 21 +/- 8; propan-2-ol, less than or equal to 17 +/- 6; butan-1-ol, less than or equal to 27 +/- 10; butan-2-ol, less than or equal to 25 +/- 8; heptan-4-ol, less than or equal to 60 +/- 20; cis-1,2-dichloroethene, 1.3 +/- 1.3; 1,1-dichloroethene, 18(-6)(+9); trichloroethene, 3.6(-1.5)(+2.0); tetrachloroethene, <1.8; and 3-chloropropene, 5.8(-2.0)(+3.0). Carbonyl products of the alcohol reactions arising after H-atom abstraction at the carbon atom to which the -OH group is attached were observed, and rate constants for this reaction pathway obtained. Significant discrepancies with the literature concern propan-2-ol, ethyl tert-butyl ether and 3-chloropropene, with our relative rate constants for these compounds being factors of ca. 2, ca. 2, and ca. 8 lower, respectively, than previously reported absolute rate constant determinations.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Univ Calif Riverside, Statewide Air Pollut Res Ctr, Riverside, CA 92521 USA}, author = {Chew, AA and Atkinson, R and ASCHMANN, SM}, biburl = {https://www.bibsonomy.org/bibtex/29c056f2a106146d8d38418091fa2bd15/gsmith}, date-added = {2010-05-04 15:01:56 -0400}, date-modified = {2010-05-04 15:02:03 -0400}, interhash = {41c0c48e03fbdd2b2fc7d01e7c3ef65e}, intrahash = {9c056f2a106146d8d38418091fa2bd15}, journal = {Journal of the Chemical Society-Faraday Transactions}, keywords = {Chemistry Constants, Detection, Ftir, Lif N2O5, Nitrate Organic-Compounds, Products, Radicals, Rate Temperature,}, language = {English}, month = Jan, number = 8, pages = {1083--1089}, pmid = {000073371000011}, rating = {0}, timestamp = {2010-06-22T19:38:51.000+0200}, title = {Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3386}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reactions+of+NO3+radicals+with+a+series+of+alcohols,+glycol+ethers,+ethers+and+chloroalkenes&ie=UTF-8&oe=UTF-8}, volume = 94, year = 1998 }