%0 Journal Article %1 ISI:000284066100003 %A Mohammadnezhad, Gholamhossein %A Amini, Mostafa M. %A Khavasi, Hamid Reza %C THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND %D 2010 %I ROYAL SOC CHEMISTRY %J DALTON TRANSACTIONS %K imported %N 45 %P 10830-10832 %R 10.1039/c0dt00983k %T A single source precursor for low temperature processing of nanocrystalline MgAl2O4 spinel: synthesis and characterization of MgAl2(mu(3)-O)(mu(2)-(OPr)-Pr-i)(4)((OPr)-Pr-i)(2)(4) %V 39 %X A novel polynuclear single-source precursor was prepared and characterized by single-crystal X-ray diffraction and multinuclear NMR spectroscopy. Nano-crystalline MgAl2O4 spinel was synthesized via sol-gel processing of MgAl2(mu(3)-O)(mu(2)-(OPr)-Pr-i)(4)((OPr)-Pr-i)(2)(4). XRD, TGA-DSC and HRTEM confirmed the formation of a spinel phase at 475 degrees C, a temperature lower than any known processing temperature for MgAl2O4.

@article{ISI:000284066100003, abstract = {{A novel polynuclear single-source precursor was prepared and characterized by single-crystal X-ray diffraction and multinuclear NMR spectroscopy. Nano-crystalline MgAl2O4 spinel was synthesized via sol-gel processing of {[}MgAl2(mu(3)-O)(mu(2)-(OPr)-Pr-i)(4)((OPr)-Pr-i)(2)](4). XRD, TGA-DSC and HRTEM confirmed the formation of a spinel phase at 475 degrees C, a temperature lower than any known processing temperature for MgAl2O4.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND}}, affiliation = {{Amini, MM (Reprint Author), Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran. Mohammadnezhad, Gholamhossein; Amini, Mostafa M.; Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran.}}, author = {Mohammadnezhad, Gholamhossein and Amini, Mostafa M. and Khavasi, Hamid Reza}, author-email = {{m-pouramini@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2d160775e16a6fcb627f6b3ad7b7eef43/hkhavasi}, cited-references = {{Boyle TJ, 2002, INORG CHEM, V41, P946, DOI 10.1021/ic0110833. BRADLEY DC, 1958, J CHEM SOC, P99, DOI 10.1039/jr9580000099. Bradley D. C., 1978, METAL ALKOXIDE. CARTS YA, 1992, LASER FOCUS WORLD, V28, P28. GUSMANO G, 1993, SENSOR ACTUAT B-CHEM, V14, P525, DOI 10.1016/0925-4005(93)85076-M. Heitz S, 2010, CHEM MATER, V22, P4563, DOI 10.1021/cm100415m. Jana S, 2009, DALTON T, P1516, DOI 10.1039/b816623d. JOHANSSON A, 2000, J CHEM SOC DA, V3, P387. Kapoor PN, 2003, J MATER CHEM, V13, P410, DOI 10.1039/b205743n. Kessler VG, 2008, ANGEW CHEM INT EDIT, V47, P8506, DOI 10.1002/anie.200803307. Kessler VG, 2009, J SOL-GEL SCI TECHN, V51, P264, DOI 10.1007/s10971-009-1946-x. Kessler VG, 2003, CHEM COMMUN, P1213, DOI 10.1039/b209168m. Koh W, 1998, CHEM VAPOR DEPOS, V4, P192, DOI 10.1002/(SICI)1521-3862(199810)04:05<192::AID-CVDE192>3.3.CO;2-D. MEESEMARKTSCHEFFEL JA, 1994, POLYHEDRON, V13, P1045, DOI 10.1016/S0277-5387(00)83030-2. MEESEMARKTSCHEFFEL JA, 1993, CHEM MATER, V5, P755, DOI 10.1021/cm00030a005. Mehrotra RC, 1996, CHEM SOC REV, V25, P1, DOI 10.1039/cs9962500001. MEHROTRA RC, 1978, INORG CHIM ACTA, V29, P131, DOI 10.1016/S0020-1693(00)89637-1. Park KY, 2006, J NANOPART RES, V8, P1075, DOI 10.1007/s11051-005-9053-6. Pazik R, 2010, INORG CHEM, V49, P2684, DOI 10.1021/ic902403f. Polarz S, 2009, CHEM MATER, V21, P3889, DOI 10.1021/cm9014223. ROCHELEAU RE, 1994, CHEM MATER, V6, P1615, DOI 10.1021/cm00046a009. SABMANNSHAUSEN J, 1993, NATURFORSCH B, V48, P7. SCHMID R, 1991, INORG CHIM ACTA, V190, P237, DOI 10.1016/S0020-1693(00)80259-5. SCHMID R, 1991, INORG CHIM ACTA, V179, P167, DOI 10.1016/S0020-1693(00)85874-0. Sheldrick G. M., 1997, SHELXL 97 PROGRAM RE. Sirio C, 1997, POLYHEDRON, V16, P1129, DOI 10.1016/S0277-5387(96)00378-6. Starikova ZA, 2004, POLYHEDRON, V23, P109, DOI 10.1016/j.poly.2003.09.031. {*}STOE CIE, 2005, STOE X AREA SOFTW VE, P67601. Suryanarayana C., 1998, XRAY DIFFRACTION PRA, p{[}50, 212]. Turova NY, 1994, J SOL-GEL SCI TECHN, V2, P17, DOI 10.1007/BF00486207. Turevskaya E. P., 2002, CHEM METAL ALKOXIDES. Veith M, 2003, Z ANORG ALLG CHEM, V629, P569, DOI 10.1002/zaac.200390092. Veith M, 1999, CHEM VAPOR DEPOS, V5, P87, DOI 10.1002/(SICI)1521-3862(199903)5:2<87::AID-CVDE87>3.3.CO;2-N. Xiaolin J., 2004, MAT SCI ENG A-STRUCT, V379, P112, DOI 10.1016/j.msea.2003.12.057. Zhang HJ, 2004, MATER LETT, V58, P1625, DOI 10.1016/j.matlet.2003.09.051.}}, doc-delivery-number = {{678IA}}, doi = {{10.1039/c0dt00983k}}, interhash = {487f4ba2382744eae22b5242d4b67d56}, intrahash = {d160775e16a6fcb627f6b3ad7b7eef43}, issn = {{1477-9226}}, journal = {{DALTON TRANSACTIONS}}, journal-iso = {{Dalton Trans.}}, keywords = {imported}, keywords-plus = {{TRANSITION-METAL ALKOXIDES; SOL-GEL SYNTHESIS; MOLECULAR-STRUCTURE; ALUMINUM ALKOXIDES; OXO-ALKOXIDES; SOURCE CVD; CHEMISTRY; NANOPARTICLES; COMPLEXES; CLUSTERS}}, language = {{English}}, number = {{45}}, number-of-cited-references = {{35}}, pages = {{10830-10832}}, publisher = {{ROYAL SOC CHEMISTRY}}, research-areas = {{Chemistry}}, researcherid-numbers = {{Mohammadnezhad, Gholamhossein/F-8582-2017}}, times-cited = {{6}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{A single source precursor for low temperature processing of nanocrystalline MgAl2O4 spinel: synthesis and characterization of {[}MgAl2(mu(3)-O)(mu(2)-(OPr)-Pr-i)(4)((OPr)-Pr-i)(2)](4)}}, type = {{Article}}, unique-id = {{ISI:000284066100003}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{11}}, volume = {{39}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2010}} }