Inproceedings,

Synthesis, characterization and catalytic properties of nanostructured porous carbon

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ZEOLITES AND RELATED MATERIALS: TRENDS, TARGETS AND CHALLENGES, PROCEEDINGS OF THE 4TH INTERNATIONAL FEZA CONFERENCE, volume 174 of Studies in Surface Science and Catalysis, page 1303-1306. SARA BURGERHARTSTRAAT 25, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, French Group Zeolites (GFZ), ELSEVIER SCIENCE BV, (2008)4th Conference of the Federation of European Zeolite Associations (FEZA), Univ Pierra Marie Curie, Paris, FRANCE, SEP 02-06, 2008.

Abstract

MCM-41, MCM-48 and FAU molecular sieves were used as template to prepare carbon nitrides (CN). The amine-functionalized CN were characterized by XRD, Raman and infrared (FTIR) spectroscopy, N-2 adsorption isotherms as well as the catalytic activity in a fine chemistry reaction was evaluated. MCM-41 is the best matrix to obtain ordered materials with a graphitic character. Also, sucrose is the best carbon precursor to obtain a pore filling of 32 wt.% compared with naphthalene and carbon tetrachloride. The nanoporous carbons studied are potentially of great importance because of their textural features and high catalytic performance. It must be correlated to the basic active sites that provide active, selective and stable catalysts to the target reaction.

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