%0 Journal Article %1 WOS:000645434400007 %A Vinnik, Denis A %A Starikov, Andrey Yu %A Zhivulin, Vladimir E %A Astapovich, Kseniya A %A Turchenko, Vitaliy A %A I, Tat'yana Zubar %A V, Sergei Trukhanov %A Kohout, Jaroslav %A Kmjec, Tomas %A Yakovenko, Olena %A Matzui, Lyudmila %A Sombra, Antonio Sergio B %A Zhou, Di %A Jotania, Rajshree B %A Singh, Charanjeet %A Yang, Yujie %A V, Alex Trukhanov %C 1155 16TH ST, NW, WASHINGTON, DC 20036 USA %D 2021 %I AMER CHEMICAL SOC %J ACS APPLIED ELECTRONIC MATERIALS %K ac anisotropy; barium conductivity; crystal crystallographic hexaferrite; magnetic permittivity} structure; {doped %N 4 %P 1583-1593 %R 10.1021/acsaelm.0c01081 %T Changes in the Structure, Magnetization, and Resistivity of BaFe12-xTixO19 %V 3 %X BaFe12-xTixO19 hexaferrites up to x = 2.00 were fabricated in an ordinary ceramic way. Crystal structure parameters were isothermally defined at 300 K from the powder XRD by the Rietveld technique. The cell constants have nonmonotonic concentration dependence with a local minimum of a similar to 5.886 angstrom and V similar to 698.75 angstrom(3) at x = 1.00. The occupation mechanism of the titanium cations is confirmed. The Mossbauer investigation confirms such localization of Ti4+. Magnetization vs field measurements were realized at 300 K. The law of approach to saturation (LAS) was applied to determine the magnetic loop characteristics. These values decrease almost monotonically with an increase in titanium concentration and temperature. The minimum magnetic values were obtained for x = 2.00 at 300 K. Ac resistivity had a nonmonotonic growth dependence. Minimum ac resistivity was fixed for x = 0.50 at 300 K. As the frequency increases, the ac resistivity decreases, as the value of the band gap. The real part of permittivity epsilon' rises constantly with increasing temperature and falls with frequency increase for all of the compositions. Changes in the structure, magnetization, and ac resistivity of BaFe12-xTixO19 were made on the basis of changing charged states of iron ions and the occupation mechanism by titanium ions.

@article{WOS:000645434400007, abstract = {BaFe12-xTixO19 hexaferrites up to x = 2.00 were fabricated in an ordinary ceramic way. Crystal structure parameters were isothermally defined at 300 K from the powder XRD by the Rietveld technique. The cell constants have nonmonotonic concentration dependence with a local minimum of a similar to 5.886 angstrom and V similar to 698.75 angstrom(3) at x = 1.00. The occupation mechanism of the titanium cations is confirmed. The Mossbauer investigation confirms such localization of Ti4+. Magnetization vs field measurements were realized at 300 K. The law of approach to saturation (LAS) was applied to determine the magnetic loop characteristics. These values decrease almost monotonically with an increase in titanium concentration and temperature. The minimum magnetic values were obtained for x = 2.00 at 300 K. Ac resistivity had a nonmonotonic growth dependence. Minimum ac resistivity was fixed for x = 0.50 at 300 K. As the frequency increases, the ac resistivity decreases, as the value of the band gap. The real part of permittivity epsilon' rises constantly with increasing temperature and falls with frequency increase for all of the compositions. Changes in the structure, magnetization, and ac resistivity of BaFe12-xTixO19 were made on the basis of changing charged states of iron ions and the occupation mechanism by titanium ions.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA}, author = {Vinnik, Denis A and Starikov, Andrey Yu and Zhivulin, Vladimir E and Astapovich, Kseniya A and Turchenko, Vitaliy A and I, Tat'yana Zubar and V, Sergei Trukhanov and Kohout, Jaroslav and Kmjec, Tomas and Yakovenko, Olena and Matzui, Lyudmila and Sombra, Antonio Sergio B and Zhou, Di and Jotania, Rajshree B and Singh, Charanjeet and Yang, Yujie and V, Alex Trukhanov}, biburl = {https://www.bibsonomy.org/bibtex/2d27518f40299966f97f7e85bfd6f3cfb/ppgfis_ufc_br}, doi = {10.1021/acsaelm.0c01081}, interhash = {87d666e63e938d7592741c1864ed3795}, intrahash = {d27518f40299966f97f7e85bfd6f3cfb}, journal = {ACS APPLIED ELECTRONIC MATERIALS}, keywords = {ac anisotropy; barium conductivity; crystal crystallographic hexaferrite; magnetic permittivity} structure; {doped}, number = 4, pages = {1583-1593}, publisher = {AMER CHEMICAL SOC}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Changes in the Structure, Magnetization, and Resistivity of BaFe12-xTixO19}, tppubtype = {article}, volume = 3, year = 2021 }