%0 Journal Article %1 Malone_2023 %A Malone, Ryan J. %A Spengler, Jonas %A Carmichael, Rachael A. %A Ngo, Khoa %A Würthner, Frank %A Chalifoux, Wesley A. %D 2023 %I American Chemical Society (ACS) %J Org. Lett. %K myown %N 1 %P 226--230 %R 10.1021/acs.orglett.2c04071 %T Synthesis and Properties of Achiral and Chiral Dipyrenoheteroles and Related Compounds %U https://doi.org/10.1021%2Facs.orglett.2c04071 %V 25 %X Achiral and chiral isomers of dipyrenoheteroles were synthesized via alkyne benzannulation. The electronic properties of these compounds were examined using cyclic voltammetry and differential pulse voltammetry. The enantiomers of the chiral isomers were separated, and their optical properties were examined in circular dichroism and circularly polarized luminescence studies. The chiral isomers exhibited a large bathochromic shift, relative to the achiral isomer, in both absorbance and fluorescence, resulting from decreased symmetry, rather than a change in the size of the backbone.

@article{Malone_2023, abstract = {Achiral and chiral isomers of dipyrenoheteroles were synthesized via alkyne benzannulation. The electronic properties of these compounds were examined using cyclic voltammetry and differential pulse voltammetry. The enantiomers of the chiral isomers were separated, and their optical properties were examined in circular dichroism and circularly polarized luminescence studies. The chiral isomers exhibited a large bathochromic shift, relative to the achiral isomer, in both absorbance and fluorescence, resulting from decreased symmetry, rather than a change in the size of the backbone.}, added-at = {2023-02-10T10:48:01.000+0100}, author = {Malone, Ryan J. and Spengler, Jonas and Carmichael, Rachael A. and Ngo, Khoa and Würthner, Frank and Chalifoux, Wesley A.}, biburl = {https://www.bibsonomy.org/bibtex/27b025574821a0c24c3b889b8b009a2da/wuerthner_group}, doi = {10.1021/acs.orglett.2c04071}, interhash = {199383540e5ad8269a1b88d3b7c40ea2}, intrahash = {7b025574821a0c24c3b889b8b009a2da}, journal = {Org. Lett.}, keywords = {myown}, month = jan, number = 1, pages = {226--230}, publisher = {American Chemical Society ({ACS})}, timestamp = {2023-02-10T10:48:01.000+0100}, title = {Synthesis and Properties of Achiral and Chiral Dipyrenoheteroles and Related Compounds}, url = {https://doi.org/10.1021%2Facs.orglett.2c04071}, volume = 25, year = 2023 }