Abstract
Early results from the JWST-MIRI guaranteed time programs on protostars
(JOYS) and disks (MINDS) are presented. Thanks to the increased sensitivity,
spectral and spatial resolution of the MIRI spectrometer, the chemical
inventory of the planet-forming zones in disks can be investigated with
unprecedented detail across stellar mass range and age. Here data are presented
for five disks, four around low-mass stars and one around a very young
high-mass star. The mid-infrared spectra show some similarities but also
significant diversity: some sources are rich in CO2, others in H2O or C2H2. In
one disk around a very low-mass star, booming C2H2 emission provides evidence
for a ``soot'' line at which carbon grains are eroded and sublimated, leading
to a rich hydrocarbon chemistry in which even di-acetylene (C4H2) and benzene
(C6H6) are detected (Tabone et al. 2023). Together, the data point to an active
inner disk gas-phase chemistry that is closely linked to the physical structure
(temperature, snowlines, presence of cavities and dust traps) of the entire
disk and which may result in varying CO2/H2O abundances and high C/O ratios >1
in some cases. Ultimately, this diversity in disk chemistry will also be
reflected in the diversity of the chemical composition of exoplanets.
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