%0 Journal Article %1 ISI:000330826300008 %A Mirzaee, Mahdi %A Norouzi, Mahmood %A Faghani, Masoomeh %A Amini, Mostafa M. %A Khavasi, Hamid Reza %C VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS %D 2014 %I SPRINGER %J TRANSITION METAL CHEMISTRY %K imported %N 1 %P 55-62 %R 10.1007/s11243-013-9773-x %T Synthesis, characterization and molecular structure of titanium alkoxide complexes with aromatic oxime ligands %V 39 %X Stoichiometric reactions of pyridine-2-aldoxime (HL1) with titanium 2-propoxide and of salicylaldoxime (H(2)L2) with titanium 2-propoxide or titanium ethoxide in toluene at room temperature resulted in the formation of Ti-2(mu-O)(mu-L)(2)(OR)(4) (for L1, R = Pr-i; for L2, R = Pr-i or Et). These complexes were all characterized by spectroscopic methods; in addition, the molecular structure of Ti-2(mu-O)(mu-L1)(2)((OPr)-Pr-i)(4) was determined by single-crystal X-ray diffraction. The titanium atoms have distorted octahedral geometries that share an apex through a bridging oxygen. Each monoanionic L1 is chelated to one titanium atom through its pyridine and oximate nitrogen atoms and to a second titanium atom through its oximate oxygen atom.

@article{ISI:000330826300008, abstract = {{Stoichiometric reactions of pyridine-2-aldoxime (HL1) with titanium 2-propoxide and of salicylaldoxime (H(2)L2) with titanium 2-propoxide or titanium ethoxide in toluene at room temperature resulted in the formation of {[}Ti-2(mu-O)(mu-L)(2)(OR)(4)] (for L1, R = Pr-i; for L2, R = Pr-i or Et). These complexes were all characterized by spectroscopic methods; in addition, the molecular structure of {[}Ti-2(mu-O)(mu-L1)(2)((OPr)-Pr-i)(4)] was determined by single-crystal X-ray diffraction. The titanium atoms have distorted octahedral geometries that share an apex through a bridging oxygen. Each monoanionic L1 is chelated to one titanium atom through its pyridine and oximate nitrogen atoms and to a second titanium atom through its oximate oxygen atom.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS}}, affiliation = {{Mirzaee, M (Reprint Author), Shahrood Univ Technol, Dept Chem, Shahrood, Iran. Mirzaee, Mahdi; Norouzi, Mahmood; Faghani, Masoomeh, Shahrood Univ Technol, Dept Chem, Shahrood, Iran. Amini, Mostafa M.; Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran.}}, author = {Mirzaee, Mahdi and Norouzi, Mahmood and Faghani, Masoomeh and Amini, Mostafa M. and Khavasi, Hamid Reza}, author-email = {{mmirzaee@shahroodut.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2190ceeac1551830650916de43505d897/hkhavasi}, cited-references = {{Aakeroy CB, 2000, CRYSTENGCOMM, DOI 10.1039/b006043g. 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Zerbib V, 1994, CHEM COMMUN, P2179.}}, doc-delivery-number = {{AA0ZQ}}, doi = {{10.1007/s11243-013-9773-x}}, eissn = {{1572-901X}}, funding-acknowledgement = {{Vice-President's Office for Research Affairs of Shahrood University of Technology; Shahid Beheshti University}}, funding-text = {{The authors thank the Vice-President's Office for Research Affairs of Shahrood University of Technology and Shahid Beheshti University for supporting this work.}}, interhash = {bc82d59f3f772c1c42c28f071d89a0c0}, intrahash = {190ceeac1551830650916de43505d897}, issn = {{0340-4285}}, journal = {{TRANSITION METAL CHEMISTRY}}, journal-iso = {{Transit. Met. Chem.}}, keywords = {imported}, keywords-plus = {{SINGLE-CRYSTAL STRUCTURE; COORDINATION CHEMISTRY; CLUSTER; BEHAVIOR; BINDING}}, language = {{English}}, month = {{FEB}}, number = {{1}}, number-of-cited-references = {{37}}, pages = {{55-62}}, publisher = {{SPRINGER}}, research-areas = {{Chemistry}}, times-cited = {{1}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization and molecular structure of titanium alkoxide complexes with aromatic oxime ligands}}, type = {{Article}}, unique-id = {{ISI:000330826300008}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{15}}, volume = {{39}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2014}} }