%0 Journal Article %1 RN349 %A Aliaga, J.A. %A Zepeda, T.N. %A Pawelec, B.N. %A Araya, J.F. %A Antunez-Garcia, J. %A Farias, M.H. %A Fuentes, S. %A Galvan, D. %A Alonso-Nunez, G. %A Gonzalez, G. %D 2017 %J Catalysis Letters %K carbon, catalysis, composites, dichalcogenides, disulfide, dqcauchile evolution, heterogeneous hidrodesulfurization, hydrodeoxygenation, hydrogen molybdenum-disulfide, nanoparticles, nanosized rhenium solvothermal sulfide, sulfides, synthesis, technetium transition-metal %N 5 %P 1243-1251 %R 10.1007/s10562-017-2024-6 %T Microspherical Res2 as a High-Performance Hydrodesulfurization Catalyst %U /brokenurl#<Go to ISI>://WOS:000400356200016 %V 147 %X An unsupported microspherical ReS2 catalyst, consisting in self-assembled nano-layers, was evaluated in the hydrodesulfurization (HDS) of 3-methylthiophene showing an excellent catalytic activity. The samples were characterized by X-ray diffraction, scanning electron microscopy, high resolution electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. These techniques revealed that the rhenium disulfide layers are confined to a 3D hierarchical structure with different stacking, slab size and bending, according to the annealing temperature (400 or 800 A degrees C). The presence of a defect-rich structure in the microspheres, with short and randomly-orientated ReS2 slabs, results in the exposure of additional edge sites, which improve the catalytic performance of this material. This microspherical ReS2 composite, with good HDS performance, is a promising catalyst for the desulfurization of fuel oils; the solvothermal reaction conditions are also useful to tune and create exotic morphologies for the design of new ReS2 catalysts.

@article{RN349, abstract = {An unsupported microspherical ReS2 catalyst, consisting in self-assembled nano-layers, was evaluated in the hydrodesulfurization (HDS) of 3-methylthiophene showing an excellent catalytic activity. The samples were characterized by X-ray diffraction, scanning electron microscopy, high resolution electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. These techniques revealed that the rhenium disulfide layers are confined to a 3D hierarchical structure with different stacking, slab size and bending, according to the annealing temperature (400 or 800 A degrees C). The presence of a defect-rich structure in the microspheres, with short and randomly-orientated ReS2 slabs, results in the exposure of additional edge sites, which improve the catalytic performance of this material. This microspherical ReS2 composite, with good HDS performance, is a promising catalyst for the desulfurization of fuel oils; the solvothermal reaction conditions are also useful to tune and create exotic morphologies for the design of new ReS2 catalysts.}, added-at = {2019-12-04T03:57:35.000+0100}, author = {Aliaga, J.A. and Zepeda, T.N. and Pawelec, B.N. and Araya, J.F. and Antunez-Garcia, J. and Farias, M.H. and Fuentes, S. and Galvan, D. and Alonso-Nunez, G. and Gonzalez, G.}, biburl = {https://www.bibsonomy.org/bibtex/2c9fb6d070f26415cc58ee4978b12270c/dqcauchile}, doi = {10.1007/s10562-017-2024-6}, interhash = {c05a0b8f80453dc5b25d506c6a408b60}, intrahash = {c9fb6d070f26415cc58ee4978b12270c}, issn = {1011-372x}, journal = {Catalysis Letters}, keywords = {carbon, catalysis, composites, dichalcogenides, disulfide, dqcauchile evolution, heterogeneous hidrodesulfurization, hydrodeoxygenation, hydrogen molybdenum-disulfide, nanoparticles, nanosized rhenium solvothermal sulfide, sulfides, synthesis, technetium transition-metal}, number = 5, pages = {1243-1251}, timestamp = {2019-12-04T03:58:17.000+0100}, title = {Microspherical Res2 as a High-Performance Hydrodesulfurization Catalyst}, type = {Journal Article}, url = {/brokenurl#<Go to ISI>://WOS:000400356200016}, volume = 147, year = 2017 }