Article,

Optical second harmonic spectroscopy of semiconductor surfaces: advances in microscopic understanding

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Surface and Interface Analysis, 31 (10): 966--986 (2001)

Abstract

Even-order non-linear optical spectroscopy has emerged as an unusually sensitive technique for non-invasive analysis of surfaces and buried interfaces of centrosymmetric materials. The forefront challenges are: to develop reliable microscopic computational methods for calculating and interpreting measured surface non-linear spectra; to relate non-linear surface spectra quantitatively to linear optical surface probes such as reflectance-difference spectroscopy (RDS); and to develop convenient methods for acquiring non-linear optical spectra over bandwidths (several electron-volts) that encompass multiple electronic surface resonances. We review recent advances in both calculation and measurement of non-linear spectra, with emphasis on reconstructed and adsorbate-covered silicon surfaces in epitaxial growth environments. Copyright © 2001 John Wiley & Sons, Ltd.

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