%0 Journal Article %1 citeulike:894055 %A Trost, Barry M. %A Matsuoka, Richard T. %D 1992 %J Synlett %K chiral-sulfur %P 27--30 %T N-Nitrosulfoximines as Chemical Chameleons for Asymmetric Synthesis %X In contrast to N-tosylsulfoximines, the relatively obscure N-nitrosulfoximines show good diastereoselectivity in alkylations and extraordinarily good leaving group properties in cyclizations via SN2 displacement. Thus, methyl phenyl N-nitrosulfoximine serves as a chiral lynchpin for construction of chiral ring systems.

@article{citeulike:894055, abstract = {In contrast to N-tosylsulfoximines, the relatively obscure N-nitrosulfoximines show good diastereoselectivity in alkylations and extraordinarily good leaving group properties in cyclizations via SN2 displacement. Thus, methyl phenyl N-nitrosulfoximine serves as a chiral lynchpin for construction of chiral ring systems.}, added-at = {2006-10-23T11:08:30.000+0200}, author = {Trost, Barry M. and Matsuoka, Richard T.}, biburl = {https://www.bibsonomy.org/bibtex/20204d97231b4dca84b2858303cd0da63/robert}, citeulike-article-id = {894055}, interhash = {594ebe1c010745f4e93b172df8aece50}, intrahash = {0204d97231b4dca84b2858303cd0da63}, journal = {Synlett}, keywords = {chiral-sulfur}, pages = {27--30}, priority = {2}, timestamp = {2006-10-23T11:08:30.000+0200}, title = {N-Nitrosulfoximines as Chemical Chameleons for Asymmetric Synthesis}, year = 1992 }