Scanning tunneling microscopy was applied to studies of adsorbates
on model catalysts at elevated pressures where dense overlayers in
equilibrium with the gas phase can be formed. A structure due an
incommensurate hexagonal overlayer is observed for CO on the Pt(111)
surface in the 200�750 Torr pressure range. This structure has not
been observed before at similar coverage under low pressure and temperature
conditions. The results illustrate the inequivalence in this case
between the study of surfaces in catalytic conditions of high pressure
and the surface science studies carried out in high vacuum.
%0 Journal Article
%1 Jensen1998
%A Jensen, John A.
%A Rider, Keith B.
%A Salmeron, Miquel
%A and Gabor A. Somorjai,
%D 1998
%J Phys. Rev. Lett.
%K science surface
%P 1228--1231
%R 10.1103/PhysRevLett.80.1228
%T High Pressure Adsorbate Structures Studied by Scanning Tunneling
Microscopy: CO on Pt(111) in Equilibrium with the Gas Phase
%V 80
%X Scanning tunneling microscopy was applied to studies of adsorbates
on model catalysts at elevated pressures where dense overlayers in
equilibrium with the gas phase can be formed. A structure due an
incommensurate hexagonal overlayer is observed for CO on the Pt(111)
surface in the 200�750 Torr pressure range. This structure has not
been observed before at similar coverage under low pressure and temperature
conditions. The results illustrate the inequivalence in this case
between the study of surfaces in catalytic conditions of high pressure
and the surface science studies carried out in high vacuum.
@article{Jensen1998,
abstract = {Scanning tunneling microscopy was applied to studies of adsorbates
on model catalysts at elevated pressures where dense overlayers in
equilibrium with the gas phase can be formed. A structure due an
incommensurate hexagonal overlayer is observed for CO on the Pt(111)
surface in the 200�750 Torr pressure range. This structure has not
been observed before at similar coverage under low pressure and temperature
conditions. The results illustrate the inequivalence in this case
between the study of surfaces in catalytic conditions of high pressure
and the surface science studies carried out in high vacuum.},
added-at = {2009-10-01T16:01:09.000+0200},
author = {Jensen, John A. and Rider, Keith B. and Salmeron, Miquel and and Gabor A. Somorjai},
biburl = {https://www.bibsonomy.org/bibtex/20b9ef0aaea86f49c91164bde5465bd75/jfischer},
doi = {10.1103/PhysRevLett.80.1228},
interhash = {6397abd44eebefff67c28b3e62b811e3},
intrahash = {0b9ef0aaea86f49c91164bde5465bd75},
journal = {Phys. Rev. Lett.},
keywords = {science surface},
pages = {1228--1231},
timestamp = {2009-10-01T16:01:11.000+0200},
title = {High Pressure Adsorbate Structures Studied by Scanning Tunneling
Microscopy: CO on Pt(111) in Equilibrium with the Gas Phase},
volume = 80,
year = 1998
}