%0 Journal Article %1 ISI:000304234200017 %A Sabounchei, Seyyed Javad %A Sarlakifar, Mehdi %A Salehzadeh, Sadegh %A Bayat, Mehdi %A Pourshahbaz, Mahbubeh %A Khavasi, Hamid Reza %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2012 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K Mercury(II) Silver(I) Theoretical X-ray complexes; crystal structure; studies} ylide; {Phosphorus %N 1 %P 131-136 %R 10.1016/j.poly.2012.02.034 %T Structural, theoretical and multinuclear NMR study of mercury(II) and silver(I) complexes with two new ambidentate phosphorus ylides %V 38 %X Reactions of new alpha-ketostabilized phosphorus ylides of the type Ph3P = CHC(O)R (R = 2,4-dichlorophenyl (O) and 4-isopropylphenyl (L-2)) with AgNO(3)and Hg(NO3)(2).H2O, using methanol as a solvent, are reported. The crystal structures of L-2 and Ag(L-2)(2)(NO3) (2) have been determined. Characterization of the obtained compounds was also performed by elemental analysis. IR, H-1, P-31 and C-13 NMR. Theoretical studies were carried out on the silver(I) complexes. It was shown that the nitrate ion shows a bonding interaction with the silver ion. (C) 2012 Elsevier Ltd. All rights reserved.

@article{ISI:000304234200017, abstract = {{Reactions of new alpha-ketostabilized phosphorus ylides of the type Ph3P = CHC(O)R (R = 2,4-dichlorophenyl (O) and 4-isopropylphenyl (L-2)) with AgNO(3)and Hg(NO3)(2).H2O, using methanol as a solvent, are reported. The crystal structures of L-2 and {[}Ag(L-2)(2)(NO3)] (2) have been determined. Characterization of the obtained compounds was also performed by elemental analysis. IR, H-1, P-31 and C-13 NMR. Theoretical studies were carried out on the silver(I) complexes. It was shown that the nitrate ion shows a bonding interaction with the silver ion. (C) 2012 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Sabounchei, SJ (Reprint Author), Bu Ali Sina Univ, Fac Chem, Hamadan 65174, Iran. Sabounchei, Seyyed Javad; Sarlakifar, Mehdi; Salehzadeh, Sadegh; Bayat, Mehdi; Pourshahbaz, Mahbubeh, Bu Ali Sina Univ, Fac Chem, Hamadan 65174, Iran. Bayat, Mehdi, Malayer Univ, Dept Chem, Fac Sci, Malayer 65174, Iran. Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran.}}, author = {Sabounchei, Seyyed Javad and Sarlakifar, Mehdi and Salehzadeh, Sadegh and Bayat, Mehdi and Pourshahbaz, Mahbubeh and Khavasi, Hamid Reza}, author-email = {{jsabounchei@yahoo.co.uk}}, biburl = {https://www.bibsonomy.org/bibtex/227f6e8e03a2bd67c4c6e834e18b3ce2e/hkhavasi}, cited-references = {{AHLRICHS R, 1989, CHEM PHYS LETT, V162, P165, DOI 10.1016/0009-2614(89)85118-8. BECKE AD, 1988, PHYS REV A, V38, P3098, DOI 10.1103/PhysRevA.38.3098. BRAVO P, 1976, J ORGANOMET CHEM, V111, P361, DOI 10.1016/S0022-328X(00)98145-2. BUCKLE J, 1973, J ORGANOMET CHEM, V49, pC17, DOI 10.1016/S0022-328X(00)84920-7. BUCKLE J, 1972, J CHEM SOC CHEM COMM, P1104, DOI 10.1039/c39720001104. 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YAMAMOTO Y, 1975, J ORGANOMET CHEM, V97, P479, DOI 10.1016/S0022-328X(00)89314-6.}}, doc-delivery-number = {{944WJ}}, doi = {{10.1016/j.poly.2012.02.034}}, funding-acknowledgement = {{Bu-AliSina University}}, funding-text = {{We are grateful to the Bu-AliSina University for a grant and Mr. Zebarjadian for recording the NMR spectra.}}, interhash = {cfbe2b9160243ac476a0cad1ac940dbc}, intrahash = {27f6e8e03a2bd67c4c6e834e18b3ce2e}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {Mercury(II) Silver(I) Theoretical X-ray complexes; crystal structure; studies} ylide; {Phosphorus}, keywords-plus = {{PALLADIUM(II) COMPLEXES; COPPER(I) CHLORIDE; O-COORDINATION; SULFONIUM; ARSONIUM; APPROXIMATION; PLATINUM(II); DERIVATIVES; CRYSTAL; HALIDES}}, language = {{English}}, month = {{MAY 11}}, number = {{1}}, number-of-cited-references = {{36}}, pages = {{131-136}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{12}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Structural, theoretical and multinuclear NMR study of mercury(II) and silver(I) complexes with two new ambidentate phosphorus ylides}}, type = {{Article}}, unique-id = {{ISI:000304234200017}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{5}}, volume = {{38}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2012}} }