Electron diffraction, X-ray powder diffraction and pair-distribution-function analyses to determine the crystal structures of Pigment Yellow 213, C23H21N5O9
The crystal structure of the nanocrystalline ? phase of Pigment Yellow 213 (P.Y. 213) was solved by a combination of single-crystal electron diffraction and X-ray powder diffraction, despite the poor crystallinity of the material. The molecules form an efficient dense packing, which explains the observed insolubility and weather fastness of the pigment. The pair-distribution function (PDF) of the ? phase is consistent with the determined crystal structure. The ? phase of P.Y. 213 shows even lower crystal quality, so extracting any structural information directly from the diffraction data is not possible. PDF analysis indicates the ? phase to have a columnar structure with a similar local structure as the ? phase and a domain size in column direction of approximately 4 nm.
%0 Journal Article
%1 Schmidt2009
%A Schmidt, Martin U.
%A Brühne, Stefan
%A Wolf, Alexandra
%A Rech, Anette
%A Brüning, Jürgen
%A Alig, Edith
%A Fink, Lothar
%A Buchsbaum, Christian
%A Glinnemann, Jürgen
%A van de Streek, Jacco
%A Gozzo, Fabia
%A Brunelli, Michela
%A Stowasser, Frank
%A Gorelik, Tatiana
%A Mugnaioli, Enrico
%A Kolb, Ute
%D 2009
%I International Union of Crystallography
%J Acta Cryst. B
%K dthcrys pdf py213 xrpd
%N 2
%P 189--199
%R 10.1107/s0108768109003759
%T Electron diffraction, X-ray powder diffraction and pair-distribution-function analyses to determine the crystal structures of Pigment Yellow 213, C23H21N5O9
%U http://dx.doi.org/10.1107/s0108768109003759
%V 65
%X The crystal structure of the nanocrystalline ? phase of Pigment Yellow 213 (P.Y. 213) was solved by a combination of single-crystal electron diffraction and X-ray powder diffraction, despite the poor crystallinity of the material. The molecules form an efficient dense packing, which explains the observed insolubility and weather fastness of the pigment. The pair-distribution function (PDF) of the ? phase is consistent with the determined crystal structure. The ? phase of P.Y. 213 shows even lower crystal quality, so extracting any structural information directly from the diffraction data is not possible. PDF analysis indicates the ? phase to have a columnar structure with a similar local structure as the ? phase and a domain size in column direction of approximately 4 nm.
@article{Schmidt2009,
abstract = {{The crystal structure of the nanocrystalline ? phase of Pigment Yellow 213 (P.Y. 213) was solved by a combination of single-crystal electron diffraction and X-ray powder diffraction, despite the poor crystallinity of the material. The molecules form an efficient dense packing, which explains the observed insolubility and weather fastness of the pigment. The pair-distribution function (PDF) of the ? phase is consistent with the determined crystal structure. The ? phase of P.Y. 213 shows even lower crystal quality, so extracting any structural information directly from the diffraction data is not possible. PDF analysis indicates the ? phase to have a columnar structure with a similar local structure as the ? phase and a domain size in column direction of approximately 4 nm.}},
added-at = {2019-03-11T21:00:05.000+0100},
author = {Schmidt, Martin U. and Br\"{u}hne, Stefan and Wolf, Alexandra and Rech, Anette and Br\"{u}ning, J\"{u}rgen and Alig, Edith and Fink, Lothar and Buchsbaum, Christian and Glinnemann, J\"{u}rgen and van de Streek, Jacco and Gozzo, Fabia and Brunelli, Michela and Stowasser, Frank and Gorelik, Tatiana and Mugnaioli, Enrico and Kolb, Ute},
biburl = {https://www.bibsonomy.org/bibtex/2346ab84fb43471c14445da2b0a48856b/fairybasslet},
citeulike-article-id = {4182363},
citeulike-linkout-0 = {http://dx.doi.org/10.1107/s0108768109003759},
citeulike-linkout-1 = {http://scripts.iucr.org/cgi-bin/paper?S0108768109003759},
doi = {10.1107/s0108768109003759},
interhash = {600217d7802a79935fe9108c933751fa},
intrahash = {346ab84fb43471c14445da2b0a48856b},
issn = {urn:issn:0108-7681},
journal = {Acta Cryst. B},
keywords = {dthcrys pdf py213 xrpd},
month = apr,
number = 2,
pages = {189--199},
posted-at = {2012-10-03 11:12:11},
priority = {2},
publisher = {International Union of Crystallography},
timestamp = {2019-03-11T21:06:37.000+0100},
title = {{Electron diffraction, X-ray powder diffraction and pair-distribution-function analyses to determine the crystal structures of Pigment Yellow 213, C23H21N5O9}},
url = {http://dx.doi.org/10.1107/s0108768109003759},
volume = 65,
year = 2009
}