Functionalized imidazolium iodide salts (ionic liquids) modified with CH2CHCH2, CH2CCH, or CH2CN groups are applied as dopants in the synthesis of CH3NH3PbI3-type perovskites together with a fumigation step. Notably, a solar cell device prepared from the perovskite film doped with the salt containing the CH2CHCH2 side-chain has a power conversion efficiency of 19.21%, which is the highest efficiency reported for perovskite solar cells involving a fumigation step. However, doping with the imidazolium salts with the CH2CCH and CH2CN groups result in perovskite layers that lead to solar cell devices with similar or lower power conversion efficiencies than the dopant-free cell.
Description
A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants - Zhang - 2017 - Advanced Materials - Wiley Online Library
%0 Journal Article
%1 ADMA:ADMA201702157
%A Zhang, Yi
%A Fei, Zhaofu
%A Gao, Peng
%A Lee, Yonghui
%A Tirani, Farzaneh Fadaei
%A Scopelliti, Rosario
%A Feng, Yaqing
%A Dyson, Paul J.
%A Nazeeruddin, Mohammad Khaja
%D 2017
%J Advanced Materials
%K dopants doping efficiency functionalization perovskite
%N 36
%P n/a--n/a
%R 10.1002/adma.201702157
%T A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants
%U http://dx.doi.org/10.1002/adma.201702157
%V 29
%X Functionalized imidazolium iodide salts (ionic liquids) modified with CH2CHCH2, CH2CCH, or CH2CN groups are applied as dopants in the synthesis of CH3NH3PbI3-type perovskites together with a fumigation step. Notably, a solar cell device prepared from the perovskite film doped with the salt containing the CH2CHCH2 side-chain has a power conversion efficiency of 19.21%, which is the highest efficiency reported for perovskite solar cells involving a fumigation step. However, doping with the imidazolium salts with the CH2CCH and CH2CN groups result in perovskite layers that lead to solar cell devices with similar or lower power conversion efficiencies than the dopant-free cell.
@article{ADMA:ADMA201702157,
abstract = {Functionalized imidazolium iodide salts (ionic liquids) modified with CH2CHCH2, CH2CCH, or CH2CN groups are applied as dopants in the synthesis of CH3NH3PbI3-type perovskites together with a fumigation step. Notably, a solar cell device prepared from the perovskite film doped with the salt containing the CH2CHCH2 side-chain has a power conversion efficiency of 19.21%, which is the highest efficiency reported for perovskite solar cells involving a fumigation step. However, doping with the imidazolium salts with the CH2CCH and CH2CN groups result in perovskite layers that lead to solar cell devices with similar or lower power conversion efficiencies than the dopant-free cell.},
added-at = {2017-09-22T09:48:41.000+0200},
author = {Zhang, Yi and Fei, Zhaofu and Gao, Peng and Lee, Yonghui and Tirani, Farzaneh Fadaei and Scopelliti, Rosario and Feng, Yaqing and Dyson, Paul J. and Nazeeruddin, Mohammad Khaja},
biburl = {https://www.bibsonomy.org/bibtex/25cdcb3fd80066a00158d65ff9fa90aa6/fabianopkm},
description = {A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants - Zhang - 2017 - Advanced Materials - Wiley Online Library},
doi = {10.1002/adma.201702157},
interhash = {ddbae95f7b4b2340e79b85f73c593df1},
intrahash = {5cdcb3fd80066a00158d65ff9fa90aa6},
issn = {1521-4095},
journal = {Advanced Materials},
keywords = {dopants doping efficiency functionalization perovskite},
number = 36,
pages = {n/a--n/a},
timestamp = {2017-09-22T09:48:41.000+0200},
title = {A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants},
url = {http://dx.doi.org/10.1002/adma.201702157},
volume = 29,
year = 2017
}