%0 Journal Article %1 hajash1998 %A Hajash, Andrew %A Carpenter, Thomas D. %A Dewers, Thomas A. %D 1998 %J Tectonophysics %K 1998 Dissolution albite compaction sand time-dependent %N 1-2 %P 93-115 %R DOI: 10.1016/S0040-1951(98)00117-6 %T Dissolution and time-dependent compaction of albite sand: experiments at 100°C and 160°C in pH-buffered organic acids and distilled water %U http://www.sciencedirect.com/science/article/B6V72-3V7J07D-N/2/62d34b1f223ef9ea8780d4b41bbdbd36 %V 295 %X Aqueous fluids are important in the diagenesis and deformation of crustal rocks. Both chemical and physical interactions are involved and often they are strongly coupled. For example, pore waters not only dissolve, transport, and precipitate chemical species, but they also substantially affect the mechanical behavior of the rocks that contain them. Stresses magnified at grain contacts by differences in pore-fluid pressure and confining pressure can, in turn, influence the rate and extent of chemical exchange. To begin investigation of these coupled systems, compaction experiments were conducted using albite sand (250-500 mum) and distilled water (pH 5.8), 0.07 M acetate (pH 4.7), and 0.07 M acetate + 0.005 M citrate (pH 4.4) solutions in a hydrothermal flow-through system at conditions that simulate diagenesis. Pore-fluid chemistry and pore-volume loss were monitored to quantify the effects of organic acids on time-dependent compaction rates. The effects of stress and fluid chemistry on the dissolution kinetics were also examined. Albite dissolution rates, monitored by steady-state fluid chemistry, increased when an effective pressure was applied, probably due to increases in total surface area caused by grain breakage at contacts. These effects were transient in distilled water, however, Si and Al concentrations remained elevated in the acetate pore fluid. The average Si-based release rates indicate approximate35% increase in reactive surface area by application of MPa. At 100°C with MPa, steady-state Si concentrations were approximate2.3 times higher in 0.07 M acetate and 5.8 times higher in 0.07 M acetate + 0.005 M citrate than in distilled water. Al increased by even larger factors (3× in the acetate buffer and 10× in the citrate solution). These changes in fluid chemistry are attributed to both pH and ligand-enhanced reactions. Albite dissolution appears to be controlled by surface complexation reactions at Al sites. Rapid dissolution of albite in the organic acid solutions is probably due to the ability of organic acid ligands to selectively complex with aluminum. Time-dependent compaction was observed at 100 and 160°C with MPa. Strain rates increased with temperature from approximate10-9 s-l at 100°C to approximate10-8 s-l at 160°C and decreased with strain in all pore fluids, especially at 100°C. Compaction rates in distilled water and in the acetate solution had similar magnitudes and strain dependencies; however, small amounts of citrate species apparently enhance compaction compared to the other fluids at similar strains. Textural data indicate that time-dependent compaction of the albite sand occurred primarily by brittle mechanisms at these temperatures. However, the deformation is clearly thermally activated and may be chemically assisted by the aqueous pore fluid.

@article{hajash1998, abstract = {Aqueous fluids are important in the diagenesis and deformation of crustal rocks. Both chemical and physical interactions are involved and often they are strongly coupled. For example, pore waters not only dissolve, transport, and precipitate chemical species, but they also substantially affect the mechanical behavior of the rocks that contain them. Stresses magnified at grain contacts by differences in pore-fluid pressure and confining pressure can, in turn, influence the rate and extent of chemical exchange. To begin investigation of these coupled systems, compaction experiments were conducted using albite sand (250-500 [mu]m) and distilled water (pH 5.8), 0.07 M acetate (pH 4.7), and 0.07 M acetate + 0.005 M citrate (pH 4.4) solutions in a hydrothermal flow-through system at conditions that simulate diagenesis. Pore-fluid chemistry and pore-volume loss were monitored to quantify the effects of organic acids on time-dependent compaction rates. The effects of stress and fluid chemistry on the dissolution kinetics were also examined. Albite dissolution rates, monitored by steady-state fluid chemistry, increased when an effective pressure was applied, probably due to increases in total surface area caused by grain breakage at contacts. These effects were transient in distilled water, however, Si and Al concentrations remained elevated in the acetate pore fluid. The average Si-based release rates indicate [approximate]35% increase in reactive surface area by application of MPa. At 100°C with MPa, steady-state Si concentrations were [approximate]2.3 times higher in 0.07 M acetate and 5.8 times higher in 0.07 M acetate + 0.005 M citrate than in distilled water. Al increased by even larger factors (3× in the acetate buffer and 10× in the citrate solution). These changes in fluid chemistry are attributed to both pH and ligand-enhanced reactions. Albite dissolution appears to be controlled by surface complexation reactions at Al sites. Rapid dissolution of albite in the organic acid solutions is probably due to the ability of organic acid ligands to selectively complex with aluminum. Time-dependent compaction was observed at 100 and 160°C with MPa. Strain rates increased with temperature from [approximate]10-9 s-l at 100°C to [approximate]10-8 s-l at 160°C and decreased with strain in all pore fluids, especially at 100°C. Compaction rates in distilled water and in the acetate solution had similar magnitudes and strain dependencies; however, small amounts of citrate species apparently enhance compaction compared to the other fluids at similar strains. Textural data indicate that time-dependent compaction of the albite sand occurred primarily by brittle mechanisms at these temperatures. However, the deformation is clearly thermally activated and may be chemically assisted by the aqueous pore fluid.}, added-at = {2009-10-08T11:05:07.000+0200}, author = {Hajash, Andrew and Carpenter, Thomas D. and Dewers, Thomas A.}, biburl = {https://www.bibsonomy.org/bibtex/2629b72c7e44a10d84cb13a28bc08cb28/aglinda}, description = {ScienceDirect - Tectonophysics : Dissolution and time-dependent compaction of albite sand: experiments at 100°C and 160°C in pH-buffered organic acids and distilled water}, doi = {DOI: 10.1016/S0040-1951(98)00117-6}, interhash = {e3bbfcb53f9e5fb843c18c0d13962a26}, intrahash = {629b72c7e44a10d84cb13a28bc08cb28}, issn = {0040-1951}, journal = {Tectonophysics}, keywords = {1998 Dissolution albite compaction sand time-dependent}, number = {1-2}, pages = {93-115}, timestamp = {2009-10-08T11:05:07.000+0200}, title = {Dissolution and time-dependent compaction of albite sand: experiments at 100°C and 160°C in pH-buffered organic acids and distilled water}, url = {http://www.sciencedirect.com/science/article/B6V72-3V7J07D-N/2/62d34b1f223ef9ea8780d4b41bbdbd36}, volume = 295, year = 1998 }