%0 Journal Article %1 Khamaganov:2001p3756 %A Khamaganov, VG %A Hites, RA %D 2001 %J Journal of Physical Chemistry A %K Alkanes, Alkenes, Atmospheric Chemistry, Hydrocarbons O-3, Oh, Organic-Compounds, Radicals, Series, %N 5 %P 815--822 %T Rate constants for the gas-phase reactions of ozone with isoprene, alpha- and beta-pinene, and limonene as a function of temperature %U http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=Papers&UT=000166845900004&SID=1ElBL%2540J11h8ojg9fIbA&Init=Yes&SrcAuth=mekentosj&mode=FullRecord&customersID=mekentosj&DestFail=http%253A%252F%252Faccess.isiproducts.com%252Fcustom_images%252Fwok_failed_auth.html %V 105 %X The rate constants for the gas-phase reactions of ozone with the biogenic hydrocarbons isoprene, alpha- and beta -pinene, and limonene were measured using the relative rate technique over the temperature range 242-363 K and at 760 Torr total pressure. Helium was the diluent gas, and the reactants were detected by on-line mass spectrometry. The following Arrhenius expressions have been determined for these reactions (in units of cm(3) molecule(-1)s(-1)): isoprene, (10.9(-2.17)(+2.70)) x 10(-15) exp-(1998 +/- 63)/T; alpha -pinene, (0.48(-0.18)(+0.29)) x 10(-15) exp-(530 +/- 150)/T; beta -pinene, (1.74(-0.36)(+0.46)) x 10(-15) exp-(1297 +/- 75)/T; and limonene, (2.95(-0.61)(+0.77)) x 10(-15) exp-(783 +/- 72)/T. The Arrhenius parameters determined here for the reactions of ozone with beta -pinene and limonene are the first to be reported.

@article{Khamaganov:2001p3756, abstract = {The rate constants for the gas-phase reactions of ozone with the biogenic hydrocarbons isoprene, alpha- and beta -pinene, and limonene were measured using the relative rate technique over the temperature range 242-363 K and at 760 Torr total pressure. Helium was the diluent gas, and the reactants were detected by on-line mass spectrometry. The following Arrhenius expressions have been determined for these reactions (in units of cm(3) molecule(-1)s(-1)): isoprene, (10.9(-2.17)(+2.70)) x 10(-15) exp[-(1998 +/- 63)/T]; alpha -pinene, (0.48(-0.18)(+0.29)) x 10(-15) exp[-(530 +/- 150)/T]; beta -pinene, (1.74(-0.36)(+0.46)) x 10(-15) exp[-(1297 +/- 75)/T]; and limonene, (2.95(-0.61)(+0.77)) x 10(-15) exp[-(783 +/- 72)/T]. The Arrhenius parameters determined here for the reactions of ozone with beta -pinene and limonene are the first to be reported.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Indiana Univ, Sch Publ {\&} Environm Affairs, Bloomington, IN 47405 USA}, author = {Khamaganov, VG and Hites, RA}, biburl = {https://www.bibsonomy.org/bibtex/279d531bd7107039af43a3709bda9534a/gsmith}, date-added = {2010-05-07 13:31:29 -0400}, date-modified = {2010-05-10 12:23:10 -0400}, interhash = {4ff76afcc01fd4ef0ceee865dc43e674}, intrahash = {79d531bd7107039af43a3709bda9534a}, journal = {Journal of Physical Chemistry A}, keywords = {Alkanes, Alkenes, Atmospheric Chemistry, Hydrocarbons O-3, Oh, Organic-Compounds, Radicals, Series,}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Journal%20of%20Physical%20Chemistry%20A/2001/Journal%20of%20Physical%20Chemistry%20A,%20105,%20815-822%202001.pdf}, month = Jan, number = 5, pages = {815--822}, pmid = {000166845900004}, rating = {0}, read = {Yes}, timestamp = {2010-06-22T19:38:46.000+0200}, title = {Rate constants for the gas-phase reactions of ozone with isoprene, alpha- and beta-pinene, and limonene as a function of temperature}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3756}, url = {http://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=Papers&UT=000166845900004&SID=1ElBL%2540J11h8ojg9fIbA&Init=Yes&SrcAuth=mekentosj&mode=FullRecord&customersID=mekentosj&DestFail=http%253A%252F%252Faccess.isiproducts.com%252Fcustom_images%252Fwok_failed_auth.html}, volume = 105, year = 2001 }