%0 Journal Article %1 Orzechowska:2002p2900 %A Orzechowska, GE %A Paulson, SE %D 2002 %J Atmospheric Environment %K Air, Alkene Aromatic-Compounds, Atmospheric Conditions, Formation Indoor Mechanism, No3 O-3, Oh Organic-Compounds, Ozonolysis, Radical, Radicals, Urban Volatile Yields, Z-But-2-Ene %N 3 %P 571--581 %T Production of OH radicals from the reactions of C-4-C-6 internal alkenes and styrenes with ozone in the gas phase %U http://www.google.com/search?client=safari&rls=en-us&q=Production+of+OH+radicals+from+the+reactions+of+C-4-C-6+internal+alkenes+and+styrenes+with+ozone+in+the+gas+phase&ie=UTF-8&oe=UTF-8 %V 36 %X OH formation from the ozonolysis reactions of seven internal alkenes with 4-6 carbons, styrene. traps-beta-methyl styrene, and alpha-methyl styrene was studied using complementary techniques. A small-ratio relative-rate technique in which small quantities of OH tracers are added to monitor OH formation yields provided the following results: traps-2-butene, 0.64 +/- 0.12; cis-2-butene, 0.33 +/- 0.05; trans-2-pentene, 0.46 +/- 0.08; cis-2-pentene, 0.29 +/- 0.06; trans-3-hexene, 0.53 +/- 0.08; cis-3-hexene, 0.36 +/- 0.07; and 2-methyl-2-butene, 0.98 +/- 0.24. For styrene, trans-beta-methyl styrene, and alpha-methyl styrene, OH yields of 0.07 +/- 0.04, 0.22 +/- 0.09, and 0.23 +/- 0.12 were measured, respectively. A second method, which monitors product formation from the OH reaction with 2-butanol was used to derive OH formation yields from 2,3-dimethyl-2-butene, 2-methyl-2-butene and cis-2-pentene. and provided yields of 0.91 +/- 0.14, 0.80 +/- 0.12, and 0.27 +/- 0.07, respectively. The results are briefly discussed in terms of the relationship between structures of these alkenes and OH formation. (C) 2002 Elsevier Science Ltd. All rights reserved.

@article{Orzechowska:2002p2900, abstract = {OH formation from the ozonolysis reactions of seven internal alkenes with 4-6 carbons, styrene. traps-beta-methyl styrene, and alpha-methyl styrene was studied using complementary techniques. A small-ratio relative-rate technique in which small quantities of OH tracers are added to monitor OH formation yields provided the following results: traps-2-butene, 0.64 +/- 0.12; cis-2-butene, 0.33 +/- 0.05; trans-2-pentene, 0.46 +/- 0.08; cis-2-pentene, 0.29 +/- 0.06; trans-3-hexene, 0.53 +/- 0.08; cis-3-hexene, 0.36 +/- 0.07; and 2-methyl-2-butene, 0.98 +/- 0.24. For styrene, trans-beta-methyl styrene, and alpha-methyl styrene, OH yields of 0.07 +/- 0.04, 0.22 +/- 0.09, and 0.23 +/- 0.12 were measured, respectively. A second method, which monitors product formation from the OH reaction with 2-butanol was used to derive OH formation yields from 2,3-dimethyl-2-butene, 2-methyl-2-butene and cis-2-pentene. and provided yields of 0.91 +/- 0.14, 0.80 +/- 0.12, and 0.27 +/- 0.07, respectively. The results are briefly discussed in terms of the relationship between structures of these alkenes and OH formation. (C) 2002 Elsevier Science Ltd. All rights reserved.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Univ Calif Los Angeles, Dept Atmospher Sci, Los Angeles, CA 90095 USA}, author = {Orzechowska, GE and Paulson, SE}, biburl = {https://www.bibsonomy.org/bibtex/27f8a184d4475f24476091aee95d14b52/gsmith}, date-added = {2010-04-22 10:47:36 -0400}, date-modified = {2010-04-22 10:48:15 -0400}, interhash = {3886d469d42796457b1739e3ecfa0aa4}, intrahash = {7f8a184d4475f24476091aee95d14b52}, journal = {Atmospheric Environment}, keywords = {Air, Alkene Aromatic-Compounds, Atmospheric Conditions, Formation Indoor Mechanism, No3 O-3, Oh Organic-Compounds, Ozonolysis, Radical, Radicals, Urban Volatile Yields, Z-But-2-Ene}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Atmospheric%20Environment/2002/Atmospheric%20Environment,%2036,%20571-581%202002.pdf}, month = Jan, number = 3, pages = {571--581}, pmid = {000173742400017}, rating = {0}, timestamp = {2010-06-22T19:39:08.000+0200}, title = {Production of OH radicals from the reactions of C-4-C-6 internal alkenes and styrenes with ozone in the gas phase}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p2900}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Production+of+OH+radicals+from+the+reactions+of+C-4-C-6+internal+alkenes+and+styrenes+with+ozone+in+the+gas+phase&ie=UTF-8&oe=UTF-8}, volume = 36, year = 2002 }