Kinetics of the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene using LIF detection
T. Berndt, I. Kind, and H. Karbach. Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics, 102 (10):
1486--1491(January 1998)
Abstract
Rate constants for the gas-phase reaction of NO3 radicals with I-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298+/-2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M --> NO3+NO2+M.Applying pseudo-first-order conditions, the rate constants for I-butene and trans-butene were found to be (1.04+/-0.11). 10(-14) and (3.74+/-0.45). 10(-13), respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03+/-0.09). 10(-11) and (5.49+/-0.47). 10(-11), respectively (unit: cm(3) molecule(-1) s(-1)).
%0 Journal Article
%1 Berndt:1998p3863
%A Berndt, T
%A Kind, I
%A Karbach, HJ
%D 1998
%J Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics
%K Alkenes, Atmospheric Chemical Chemistry, Coefficient, Constants Formation, Kinetics, Low-Pressures, No3 Organic-Compounds, Oxirane Radicals, Rate
%N 10
%P 1486--1491
%T Kinetics of the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene using LIF detection
%U http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reaction+of+NO3+radicals+with+1-butene,+trans-butene,+2-methyl-2-butene+and+2,3-dimethyl-2-butene+using+LIF+detection&ie=UTF-8&oe=UTF-8
%V 102
%X Rate constants for the gas-phase reaction of NO3 radicals with I-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298+/-2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M --> NO3+NO2+M.Applying pseudo-first-order conditions, the rate constants for I-butene and trans-butene were found to be (1.04+/-0.11). 10(-14) and (3.74+/-0.45). 10(-13), respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03+/-0.09). 10(-11) and (5.49+/-0.47). 10(-11), respectively (unit: cm(3) molecule(-1) s(-1)).
@article{Berndt:1998p3863,
abstract = {Rate constants for the gas-phase reaction of NO3 radicals with I-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298+/-2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M --> NO3+NO2+M.Applying pseudo-first-order conditions, the rate constants for I-butene and trans-butene were found to be (1.04+/-0.11). 10(-14) and (3.74+/-0.45). 10(-13), respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03+/-0.09). 10(-11) and (5.49+/-0.47). 10(-11), respectively (unit: cm(3) molecule(-1) s(-1)).},
added-at = {2010-06-22T19:38:37.000+0200},
affiliation = {Inst Tropospharenforsch EV, D-04303 Leipzig, Germany},
author = {Berndt, T and Kind, I and Karbach, HJ},
biburl = {https://www.bibsonomy.org/bibtex/29176a07e0697a8cde8689eb558215bb9/gsmith},
date-added = {2010-05-18 10:07:06 -0400},
date-modified = {2010-05-18 10:07:13 -0400},
interhash = {8a35ef68fe5f3bc592ff8f9e42f7b355},
intrahash = {9176a07e0697a8cde8689eb558215bb9},
journal = {Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics},
keywords = {Alkenes, Atmospheric Chemical Chemistry, Coefficient, Constants Formation, Kinetics, Low-Pressures, No3 Organic-Compounds, Oxirane Radicals, Rate},
language = {English},
month = Jan,
number = 10,
pages = {1486--1491},
pmid = {000076550500015},
rating = {0},
timestamp = {2010-06-22T19:39:23.000+0200},
title = {Kinetics of the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene using LIF detection},
uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3863},
url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetics+of+the+gas-phase+reaction+of+NO3+radicals+with+1-butene,+trans-butene,+2-methyl-2-butene+and+2,3-dimethyl-2-butene+using+LIF+detection&ie=UTF-8&oe=UTF-8},
volume = 102,
year = 1998
}