%0 Journal Article %1 nevzorov_magic_2003 %A Nevzorov, Alexander A %A Opella, Stanley J %D 2003 %J J. Magn. Reson. %K Biomolecular,Computer Control,Signal Isotopes,Nuclear Labels Magnetic Processing,Spin Resonance,Protons,Quality Simulation,Computer-Assisted,Crystallography,Leucine,Magnetics,Models,Molecular,Nitrogen %N 1 %P 182--186 %T A "magic sandwich" pulse sequence with reduced offset dependence for high-resolution separated local field spectroscopy %V 164 %X A pulse sequence for high resolution separated local field spectroscopy based on "magic sandwich" elements is demonstrated on a single crystal sample. Simulations and experimental results show that this pulse sequence has a reduced frequency offset dependence compared to PISEMA (polarization inversion spin exchange at the magic angle). As a result, it has a larger effective range of homonuclear decoupling, reduced zero-frequency spectral distortions, and more reliable scale factors for individual resonances. In addition, it is easier to setup on commercial spectrometers.

@article{nevzorov_magic_2003, abstract = {A pulse sequence for high resolution separated local field spectroscopy based on "magic sandwich" elements is demonstrated on a single crystal sample. Simulations and experimental results show that this pulse sequence has a reduced frequency offset dependence compared to PISEMA (polarization inversion spin exchange at the magic angle). As a result, it has a larger effective range of homonuclear decoupling, reduced zero-frequency spectral distortions, and more reliable scale factors for individual resonances. In addition, it is easier to setup on commercial spectrometers.}, added-at = {2017-03-14T02:48:56.000+0100}, author = {Nevzorov, Alexander A and Opella, Stanley J}, biburl = {https://www.bibsonomy.org/bibtex/2a768208240cb864bc6b3bd67cedc3339/nmrresource}, interhash = {be812cda36db4ec411c2e862ba917959}, intrahash = {a768208240cb864bc6b3bd67cedc3339}, issn = {1090-7807}, journal = {J. Magn. Reson.}, keywords = {Biomolecular,Computer Control,Signal Isotopes,Nuclear Labels Magnetic Processing,Spin Resonance,Protons,Quality Simulation,Computer-Assisted,Crystallography,Leucine,Magnetics,Models,Molecular,Nitrogen}, month = sep, number = 1, pages = {182--186}, pmid = {12932472}, timestamp = {2017-03-14T02:49:21.000+0100}, title = {{A "magic sandwich" pulse sequence with reduced offset dependence for high-resolution separated local field spectroscopy}}, volume = 164, year = 2003 }