Single crystals of Nd:La3Ga5SiO14 (NLGS) and Nd:La3Ga5.5Ta0.5O14 (NLGT)
were grown by Czochralski method. Both crystals exhibit a langasite structure (space group D-3(2) (P321) with Z = 1), whose general formula
is A(3)BC(2)D(3)O(14), where A, B, C and D represent the dodecahedral,
octahedral and tetrahedral positions, respectively. The adding of low
content of Nd does not change the crystal structure. Although they are
isostructural, the distribution of atoms among the symmetric sites is
different. While NLGT exhibits a perfect orderly structure, NLGS
exhibits an intrinsically disordered structure due to the random
distribution of Ga and Si atoms at the C-3(2) symmetry sites. To
understand what changes occur in the phonon distribution when Ta
replaces Si, we recorded and analyzed room temperature polarized Raman
spectra. We observe 8A(1)+18E modes for NLGS and 10A(1)+13E for NLGT
crystals. When Si is substituted by Ta, we observe that the wavenumber
of some modes related to vibrations involving Ga and O atoms decreases.
This agrees with the fact that the Ga-O bonds are shorter in NLGS than
in NLGT.
%0 Journal Article
%1 WOS:000393097900005
%A Na-Na, Zhang
%A Ji-Yang, Wang
%A Xiao-Ru, Pan
%A Ming-Jun, Song
%A dos Santos, Clenilton Costa
%A da Guedes, Ilde Guedes
%C FUIJAN INST RES STRUCT MATTER, CHINESE ACAD SCIENCES, FUZHOU, FUJIAN
350002, PEOPLES R CHINA
%D 2016
%I CHINESE JOURNAL STRUCTURAL CHEMISTRY
%J CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
%K Raman langasite method; piezoelectric} scattering; structure; {Czochralski
%N 11
%P 1673-1678
%R 10.14102/j.cnki.0254-5861.2011-1200
%T Raman Spectra of Nd:La3Ga5SiO14 and Nd:La3Ga5.5Ta0.5O14 Crystals
%V 35
%X Single crystals of Nd:La3Ga5SiO14 (NLGS) and Nd:La3Ga5.5Ta0.5O14 (NLGT)
were grown by Czochralski method. Both crystals exhibit a langasite structure (space group D-3(2) (P321) with Z = 1), whose general formula
is A(3)BC(2)D(3)O(14), where A, B, C and D represent the dodecahedral,
octahedral and tetrahedral positions, respectively. The adding of low
content of Nd does not change the crystal structure. Although they are
isostructural, the distribution of atoms among the symmetric sites is
different. While NLGT exhibits a perfect orderly structure, NLGS
exhibits an intrinsically disordered structure due to the random
distribution of Ga and Si atoms at the C-3(2) symmetry sites. To
understand what changes occur in the phonon distribution when Ta
replaces Si, we recorded and analyzed room temperature polarized Raman
spectra. We observe 8A(1)+18E modes for NLGS and 10A(1)+13E for NLGT
crystals. When Si is substituted by Ta, we observe that the wavenumber
of some modes related to vibrations involving Ga and O atoms decreases.
This agrees with the fact that the Ga-O bonds are shorter in NLGS than
in NLGT.
@article{WOS:000393097900005,
abstract = {Single crystals of Nd:La3Ga5SiO14 (NLGS) and Nd:La3Ga5.5Ta0.5O14 (NLGT)
were grown by Czochralski method. Both crystals exhibit a langasite structure (space group D-3(2) (P321) with Z = 1), whose general formula
is A(3)BC(2)D(3)O(14), where A, B, C and D represent the dodecahedral,
octahedral and tetrahedral positions, respectively. The adding of low
content of Nd does not change the crystal structure. Although they are
isostructural, the distribution of atoms among the symmetric sites is
different. While NLGT exhibits a perfect orderly structure, NLGS
exhibits an intrinsically disordered structure due to the random
distribution of Ga and Si atoms at the C-3(2) symmetry sites. To
understand what changes occur in the phonon distribution when Ta
replaces Si, we recorded and analyzed room temperature polarized Raman
spectra. We observe 8A(1)+18E modes for NLGS and 10A(1)+13E for NLGT
crystals. When Si is substituted by Ta, we observe that the wavenumber
of some modes related to vibrations involving Ga and O atoms decreases.
This agrees with the fact that the Ga-O bonds are shorter in NLGS than
in NLGT.},
added-at = {2022-05-23T20:00:14.000+0200},
address = {FUIJAN INST RES STRUCT MATTER, CHINESE ACAD SCIENCES, FUZHOU, FUJIAN
350002, PEOPLES R CHINA},
author = {Na-Na, Zhang and Ji-Yang, Wang and Xiao-Ru, Pan and Ming-Jun, Song and dos Santos, Clenilton Costa and da Guedes, Ilde Guedes},
biburl = {https://www.bibsonomy.org/bibtex/2b604aaaa1f23dc6e2b38d5610970ecdf/ppgfis_ufc_br},
doi = {10.14102/j.cnki.0254-5861.2011-1200},
interhash = {326721268e10d1e8cf47e94bd08832a1},
intrahash = {b604aaaa1f23dc6e2b38d5610970ecdf},
issn = {0254-5861},
journal = {CHINESE JOURNAL OF STRUCTURAL CHEMISTRY},
keywords = {Raman langasite method; piezoelectric} scattering; structure; {Czochralski},
number = 11,
pages = {1673-1678},
publisher = {CHINESE JOURNAL STRUCTURAL CHEMISTRY},
pubstate = {published},
timestamp = {2022-05-23T20:00:14.000+0200},
title = {Raman Spectra of Nd:La3Ga5SiO14 and Nd:La3Ga5.5Ta0.5O14 Crystals},
tppubtype = {article},
volume = 35,
year = 2016
}