%0 Journal Article %1 citeulike:3016424 %A Ferrell, R. T. %A Himmelblau, D. M. %C University of Texas, Austin, Texas %D 1967 %J AIChE Journal %K material-properties, measurement 80a20-heat-and-mass-transfer diffusivity %N 4 %P 702--708 %R 10.1002/aic.690130421 %T Diffusion coefficients of hydrogen and helium in water %U http://swiki/display/lib/Diffusion+Coefficients+of+Hydrogen+and+Helium+in+Water %V 13 %X Measurements of laminar dispersion in a capillary have been used to determine the molecular diffusion coefficients of hydrogen and helium dissolved in water over the temperature range of 10° to 55°C. Literature correlations did not predict realistic values of the diffusivities for the hydrogen - water and helium - water binaries. A statistical analysis of the experimental diffusion coefficients indicated that they could be related to the absolute temperature by a semiempirical correlation, which may be considered an extension of the well-known Wilke-Chang correlation. This relation was based on the absolute reaction rate model of liquids.

@article{citeulike:3016424, abstract = {{Measurements of laminar dispersion in a capillary have been used to determine the molecular diffusion coefficients of hydrogen and helium dissolved in water over the temperature range of 10° to 55°C. Literature correlations did not predict realistic values of the diffusivities for the hydrogen - water and helium - water binaries. A statistical analysis of the experimental diffusion coefficients indicated that they could be related to the absolute temperature by a semiempirical correlation, which may be considered an extension of the well-known Wilke-Chang correlation. This relation was based on the absolute reaction rate model of liquids.}}, added-at = {2017-06-29T07:13:07.000+0200}, address = {University of Texas, Austin, Texas}, author = {Ferrell, R. T. and Himmelblau, D. M.}, biburl = {https://www.bibsonomy.org/bibtex/2bf37e8a5a9e4425b87b9ef65ec952e73/gdmcbain}, citeulike-article-id = {3016424}, citeulike-attachment-1 = {ferrell_67_diffusion_33744.pdf; /pdf/user/gdmcbain/article/3016424/33744/ferrell_67_diffusion_33744.pdf; 0e6f3259dc1a8ac3bfc12ad94cac4f470de1bcdb}, citeulike-linkout-0 = {http://swiki/display/lib/Diffusion+Coefficients+of+Hydrogen+and+Helium+in+Water}, citeulike-linkout-1 = {http://dx.doi.org/10.1002/aic.690130421}, citeulike-linkout-2 = {http://www3.interscience.wiley.com/cgi-bin/abstract/109073924/ABSTRACT}, comment = {(private-note)Holdings: SBR lib}, doi = {10.1002/aic.690130421}, file = {ferrell_67_diffusion_33744.pdf}, interhash = {378f915bec7aabd39d841a6694406db8}, intrahash = {bf37e8a5a9e4425b87b9ef65ec952e73}, journal = {AIChE Journal}, keywords = {material-properties, measurement 80a20-heat-and-mass-transfer diffusivity}, number = 4, pages = {702--708}, posted-at = {2008-07-18 07:18:22}, priority = {2}, timestamp = {2021-04-06T00:03:16.000+0200}, title = {{Diffusion coefficients of hydrogen and helium in water}}, url = {http://swiki/display/lib/Diffusion+Coefficients+of+Hydrogen+and+Helium+in+Water}, volume = 13, year = 1967 }