%0 Journal Article %1 WOS:000089925000008 %A Varela, AT %A Melo, FEA %A Neto, NMB %A Freire, PTC %A Guedes, I %A Sasaki, JM %A Mendes, J %C BAFFINS LANE CHICHESTER, W SUSSEX PO19 1UD, ENGLAND %D 2000 %I JOHN WILEY & SONS LTD %J JOURNAL OF RAMAN SPECTROSCOPY %K imported %N 10 %P 915-919 %R 10.1002/1097-4555(200010)31:10<915::AID-JRS617>3.0.CO;2-S %T Metastable ferroelectric phase in potassium dihydrogen phosphate induced by a static electric field %V 31 %X Raman scattering experiments show that potassium dihydrogen phosphate crystals undergo a metastable ferroelectric phase transition induced by a static electric field at 119 K. Qualitative changes occur in the Raman spectra of all possible scattering geometries for applied d.c. electric field intensities of the order of 4 kV cm(-1). The phase transition is induced by rotation of phosphate ions changing from C-2(Z) local sites symmetries to sigma(upsilon)(YZ) sites maintaining the same factor group C-2 upsilon. An assignment of the modes in the metastable phase is presented. Copyright (C) 2000 John Whey & Sons, Ltd.

@article{WOS:000089925000008, abstract = {Raman scattering experiments show that potassium dihydrogen phosphate crystals undergo a metastable ferroelectric phase transition induced by a static electric field at 119 K. Qualitative changes occur in the Raman spectra of all possible scattering geometries for applied d.c. electric field intensities of the order of 4 kV cm(-1). The phase transition is induced by rotation of phosphate ions changing from C-2(Z) local sites symmetries to sigma(upsilon)(YZ) sites maintaining the same factor group C-2 upsilon. An assignment of the modes in the metastable phase is presented. Copyright (C) 2000 John Whey & Sons, Ltd.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {BAFFINS LANE CHICHESTER, W SUSSEX PO19 1UD, ENGLAND}, author = {Varela, AT and Melo, FEA and Neto, NMB and Freire, PTC and Guedes, I and Sasaki, JM and Mendes, J}, biburl = {https://www.bibsonomy.org/bibtex/2d251c2b6c6e6cecd142b1dd85569456c/ppgfis_ufc_br}, doi = {10.1002/1097-4555(200010)31:10<915::AID-JRS617>3.0.CO;2-S}, interhash = {6e078f4fb12150bb2763c9b2bd399107}, intrahash = {d251c2b6c6e6cecd142b1dd85569456c}, issn = {0377-0486}, journal = {JOURNAL OF RAMAN SPECTROSCOPY}, keywords = {imported}, number = 10, pages = {915-919}, publisher = {JOHN WILEY & SONS LTD}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Metastable ferroelectric phase in potassium dihydrogen phosphate induced by a static electric field}, tppubtype = {article}, volume = 31, year = 2000 }