A high-pressure Raman scattering study of the tungstate Al-2(WO4)(3) is
presented. This study showed the onset of two reversible phase
transitions at 0.28 +/- 0.07 and 2.8 +/- 0.1 GPa. The pressure evolution
of Raman bands provides strong evidences that both the transitions
involve rotations/tilts of nearly rigid tungstate tetrahedra and that
the structure of the stable phase in the 0.28-2.8 GPa range may be the
same as the structure of the ambient pressure, low-temperature
monoclinic (C-2h(5)), ferroelastic phase of Al-2(WO4)(3). (C) 2004
Elsevier Inc. All rights reserved.
%0 Journal Article
%1 WOS:000221769300029
%A Maczka, M
%A Paraguassu, W
%A Souza, AG
%A Freire, PTC
%A Mendes, J
%A Melo, FEA
%A Hanuza, J
%C 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA
%D 2004
%I ACADEMIC PRESS INC ELSEVIER SCIENCE
%J JOURNAL OF SOLID STATE CHEMISTRY
%K Raman phase pressure; spectra} transition; {high
%N 6
%P 2002-2006
%R 10.1016/j.jssc.2004.01.021
%T High-pressure Raman study of Al-2(WO4)(3)
%V 177
%X A high-pressure Raman scattering study of the tungstate Al-2(WO4)(3) is
presented. This study showed the onset of two reversible phase
transitions at 0.28 +/- 0.07 and 2.8 +/- 0.1 GPa. The pressure evolution
of Raman bands provides strong evidences that both the transitions
involve rotations/tilts of nearly rigid tungstate tetrahedra and that
the structure of the stable phase in the 0.28-2.8 GPa range may be the
same as the structure of the ambient pressure, low-temperature
monoclinic (C-2h(5)), ferroelastic phase of Al-2(WO4)(3). (C) 2004
Elsevier Inc. All rights reserved.
@article{WOS:000221769300029,
abstract = {A high-pressure Raman scattering study of the tungstate Al-2(WO4)(3) is
presented. This study showed the onset of two reversible phase
transitions at 0.28 +/- 0.07 and 2.8 +/- 0.1 GPa. The pressure evolution
of Raman bands provides strong evidences that both the transitions
involve rotations/tilts of nearly rigid tungstate tetrahedra and that
the structure of the stable phase in the 0.28-2.8 GPa range may be the
same as the structure of the ambient pressure, low-temperature
monoclinic (C-2h(5)), ferroelastic phase of Al-2(WO4)(3). (C) 2004
Elsevier Inc. All rights reserved.},
added-at = {2022-05-23T20:00:14.000+0200},
address = {525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA},
author = {Maczka, M and Paraguassu, W and Souza, AG and Freire, PTC and Mendes, J and Melo, FEA and Hanuza, J},
biburl = {https://www.bibsonomy.org/bibtex/2d80dac17712b444cd215df5435d6a177/ppgfis_ufc_br},
doi = {10.1016/j.jssc.2004.01.021},
interhash = {f92cb24d05de151eb11e1d962442ed55},
intrahash = {d80dac17712b444cd215df5435d6a177},
issn = {0022-4596},
journal = {JOURNAL OF SOLID STATE CHEMISTRY},
keywords = {Raman phase pressure; spectra} transition; {high},
number = 6,
pages = {2002-2006},
publisher = {ACADEMIC PRESS INC ELSEVIER SCIENCE},
pubstate = {published},
timestamp = {2022-05-23T20:00:14.000+0200},
title = {High-pressure Raman study of Al-2(WO4)(3)},
tppubtype = {article},
volume = 177,
year = 2004
}