%0 Journal Article %1 ISI:000249175100011 %A Amini, Mostafa M. %A Azadmeher, Amirreza %A Khavasi, Hamid Reza %A Ng, S. W. %C PO BOX 564, 1001 LAUSANNE, SWITZERLAND %D 2007 %I ELSEVIER SCIENCE SA %J JOURNAL OF ORGANOMETALLIC CHEMISTRY %K acid; carboxylate; crystal organotin; structure} {anthracenecarboxylic %N 18 %P 3922-3930 %R 10.1016/j.jorganchem.2007.05.049 %T Synthesis, characterization, and molecular structures of di- and triorganotin(IV) complexes with 9-anthracenecarboxylic acid: The structural diversity in organotin 9-anthracenecarboxylates %V 692 %X The di- and triorganotin(IV) derivatives of anthracenecarboxylic acid, Ph2MeSnOC(O)C14H9 (2), Me3SnOC(O)C14H9 (3), Me2SnOC(O)C14H9(2)center dot CH3OH (4) Ph3SnOC(O)C14H9 center dot CH3OH (5), Ph2EtSnOC(O)C14H9 (6), Ph2SnOC(O)(C14H9)(2) (7) and PhMe2SnOC(O)C14H9 (8) were synthesized by the reaction of Ph2MeSnI, Me3SnCl, Me2SnCl2, Ph3SnCl, Ph(2)EtSnl, Ph2SnCl2, and PhMe2SnI with 9-anthracenecarboxylic acid, respectively, with the aid of potassium iso-propoxide. All complexes were characterized by elemental analysis, mass spectrometry, IR, H-1, C-13 and Sn-119 NMR spectroscopes. The molecular structures of complexes 2, 3 and 4 were determined by single crystal X-ray analysis. The X-ray structures reveal that complex 2 and 3 adopt a polymeric trans-C3SnO2 trigonal bipyamidal configuration with the oxygen atoms occupying axial positions. Complex 4 adopts a monomeric structure with two carboxylates coordinated to tin in a monodentate form from axial and equatorial positions, and with the coordination number raised to five as the methanol occupies the apical position of the trigonal bipyramid. (c) 2007 Elsevier B.V. All rights reserved.

@article{ISI:000249175100011, abstract = {{The di- and triorganotin(IV) derivatives of anthracenecarboxylic acid, Ph2MeSnOC(O)C14H9 (2), Me3SnOC(O)C14H9 (3), Me2Sn{[}OC(O)C14H9](2)center dot CH3OH (4) Ph3SnOC(O)C14H9 center dot CH3OH (5), Ph2EtSnOC(O)C14H9 (6), Ph2Sn{[}OC(O)(C14H9)](2) (7) and PhMe2SnOC(O)C14H9 (8) were synthesized by the reaction of Ph2MeSnI, Me3SnCl, Me2SnCl2, Ph3SnCl, Ph(2)EtSnl, Ph2SnCl2, and PhMe2SnI with 9-anthracenecarboxylic acid, respectively, with the aid of potassium iso-propoxide. All complexes were characterized by elemental analysis, mass spectrometry, IR, H-1, C-13 and Sn-119 NMR spectroscopes. The molecular structures of complexes 2, 3 and 4 were determined by single crystal X-ray analysis. The X-ray structures reveal that complex 2 and 3 adopt a polymeric trans-C3SnO2 trigonal bipyamidal configuration with the oxygen atoms occupying axial positions. Complex 4 adopts a monomeric structure with two carboxylates coordinated to tin in a monodentate form from axial and equatorial positions, and with the coordination number raised to five as the methanol occupies the apical position of the trigonal bipyramid. (c) 2007 Elsevier B.V. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{PO BOX 564, 1001 LAUSANNE, SWITZERLAND}}, affiliation = {{Amini, MM (Reprint Author), Shahid Beheshti Univ Med Sci, Dept Chem, Tehran 1983963113, Iran. Shahid Beheshti Univ Med Sci, Dept Chem, Tehran 1983963113, Iran. Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia.}}, author = {Amini, Mostafa M. and Azadmeher, Amirreza and Khavasi, Hamid Reza and Ng, S. W.}, author-email = {{m-pouramini@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2e7845320862e779ff563c3b14f3590cf/hkhavasi}, cited-references = {{Amini MM, 2003, HETEROATOM CHEM, V14, P18, DOI 10.1002/hc.10059. Amini MM, 2003, ACTA CRYSTALLOGR E, V59, pM847, DOI 10.1107/S1600536803019299. AMINI MM, 1989, J ORGANOMET CHEM, V365, P103, DOI 10.1016/0022-328X(89)87171-2. Amini MM, 2006, ACTA CRYSTALLOGR E, V62, pM2427, DOI 10.1107/S1600536806034672. BASU TS, 2002, J ORGANOMET CHEM, V654, P100, DOI 10.1016/S0022-328X(02)01387-6. Baul TSB, 2005, J ORGANOMET CHEM, V690, P1581, DOI 10.1016/j.organchem.2004.12.030. Baul T. S. B., 2006, POLYHEDRON, V25, P3448. Benetollo F, 2005, J ORGANOMET CHEM, V690, P1994, DOI 10.1016/j.jorganchem.2004.11.034. Chandrasekhar V, 2002, COORDIN CHEM REV, V235, P1, DOI 10.1016/S0010-8545(02)00178-9. CHIN H, 1973, J CRYST MOL STRUCT, V3, P285. Dakternieks D, 2003, ORGANOMETALLICS, V22, P4599, DOI 10.1021/om0340140. DAVISON A, 1970, J ORGANOMET CHEM, V23, P407, DOI 10.1016/S0022-328X(00)92954-1. Garcia-Zarracino R, 2003, INORG CHEM, V42, P3835, DOI 10.1021/ic026270v. Gielen M, 2005, APPL ORGANOMET CHEM, V19, P440, DOI 10.1002/aoc.771. GIELEN M, 1994, ORGANOMETALLICS, V13, P2849, DOI 10.1021/om00019a047. Gielen M, 2002, APPL ORGANOMET CHEM, V16, P481, DOI 10.1002/aoc.331. GIELEN M, 2000, J INORG BIOCHEM, V79, P39. HO BYK, 1973, INORG CHEM, V12, P1552, DOI 10.1021/ic50125a016. HOLECEK J, 1986, J ORGANOMET CHEM, V315, P299, DOI 10.1016/0022-328X(86)80450-8. HOLECEK J, 1990, COLLECT CZECH CHEM C, V55, P1193. Holems R. R., 1989, ACCOUNTS CHEM RES, V22, P190. Kapoor R, 2003, APPL ORGANOMET CHEM, V17, P600, DOI 10.1002/aoc.480. Kemmer M, 2000, J ORGANOMET CHEM, V608, P63, DOI 10.1016/S0022-328X(00)00367-3. KLUWER C, 1995, INT TABLES FOE XRA C. KRIGMAN MR, 1984, NEUROTOXICOLOGY, V5, P129. LOCKHART TP, 1986, INORG CHEM, V25, P892, DOI 10.1021/ic00227a002. LYCKA A, 1984, COLLECT CZECH CHEM C, V49, P2903, DOI 10.1135/cccc19842903. Ma CL, 2006, INORG CHIM ACTA, V359, P4179, DOI 10.1016/j.ica.2006.07.001. MA CL, 2006, POLYHEDRON, V20, P30. MOLLOY KC, 1984, J ORGANOMET CHEM, V267, P237, DOI 10.1016/0022-328X(84)80194-1. MOLLOY KC, 1986, POLYHEDRON, V5, P959, DOI 10.1016/S0277-5387(00)80136-9. MOLLOY KC, 1986, J CHEM SOC DA, V1259. NG SW, 1988, J ORGANOMET CHEM, V345, P59, DOI 10.1016/0022-328X(88)80234-1. Prabusankar G, 2004, ORGANOMETALLICS, V23, P5644, DOI 10.1021/om049584u. SANDHU GK, 1992, J ORGANOMET CHEM, V430, P15, DOI 10.1016/0022-328X(92)80091-B. Schurmann M, 1999, J ORGANOMET CHEM, V584, P103, DOI 10.1016/S0022-328X(99)00103-5. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. SMITH PJ, 1986, INORG CHEM, V25, P2495, DOI 10.1021/ic00235a005. Smith P. J., 1981, J ORGANOMET CHEM LIB, V12, P97. STOE, 2005, X RED VERSION 1 28B. STOE, 2004, X SHAPE VERSION 2 05. STOE, 2000, X STEP 32 VERSION 1. STOE, 2004, X AREA VERSION 1 30. TIEKINK ER, 1995, J ORGANOMET CHEM, V497, P247. TIEKINK ERT, 1991, APPL ORGANOMET CHEM, V5, P1, DOI 10.1002/aoc.590050102. Tiekink E. R. T., 1994, TRENDS ORGANOMET CHE, V1, P71. Willem R, 1998, ORGANOMETALLICS, V17, P5758, DOI 10.1021/om980504u. Yin HD, 2006, J ORGANOMET CHEM, V691, P1235, DOI 10.1016/j.jorganchem.2005.11.062. Zhang RF, 2005, J ORGANOMET CHEM, V690, P4049, DOI 10.1016/j.jorganchem.2005.06.007. Zubieta JA, 1978, PROG INORG CHEM, V24, P251, DOI 10.1002/9780470166253.ch5.}}, doc-delivery-number = {{206HS}}, doi = {{10.1016/j.jorganchem.2007.05.049}}, interhash = {ae02667a2e3a4e8fc05ea062b4ae2c5c}, intrahash = {e7845320862e779ff563c3b14f3590cf}, issn = {{0022-328X}}, journal = {{JOURNAL OF ORGANOMETALLIC CHEMISTRY}}, journal-iso = {{J. Organomet. Chem.}}, keywords = {acid; carboxylate; crystal organotin; structure} {anthracenecarboxylic}, keywords-plus = {{SN-119 NMR-SPECTRA; CRYSTAL-STRUCTURES; SOLID-STATE; CARBOXYLATES; DERIVATIVES; CHEMISTRY; MOIETIES; ACETATE; C-13; TIN}}, language = {{English}}, month = {{AUG 15}}, number = {{18}}, number-of-cited-references = {{50}}, pages = {{3922-3930}}, publisher = {{ELSEVIER SCIENCE SA}}, research-areas = {{Chemistry}}, researcherid-numbers = {{NG, Seik Weng/A-3372-2009}}, times-cited = {{12}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization, and molecular structures of di- and triorganotin(IV) complexes with 9-anthracenecarboxylic acid: The structural diversity in organotin 9-anthracenecarboxylates}}, type = {{Article}}, unique-id = {{ISI:000249175100011}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{3}}, volume = {{692}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Chemistry, Organic}}, year = {{2007}} }