%0 Journal Article %1 Pigulski_2022 %A Pigulski, Bartłomiej %A Shoyama, Kazutaka %A Sun, Meng-Jia %A Würthner, Frank %D 2022 %I American Chemical Society (ACS) %J J. Am. Chem. Soc. %K myown %N 13 %P 5718--5722 %R 10.1021/jacs.2c00142 %T Fluorescence Enhancement by Supramolecular Sequestration of a C54-Nanographene Trisimide by Hexabenzocoronene %U https://doi.org/10.1021%2Fjacs.2c00142 %V 144 %X A supramolecular trilayer nanographene complex consisting of a newly synthesized D3h-symmetric C 54-nanographene trisimide (NTI 1) and two hexabenzocoronenes (HBC) has been obtained by self-assembly. This 1:2 complex is structurally well- defined according to UV/vis and single crystal X-ray studies and exhibits high thermodynamic stability even in polar halogenated solvents. Complexation of NTI 1 by two HBC molecules protects the NTI 1 π-surface efficiently from oxygen quenching, thereby leading to a sequestration-induced fluorescence enhancement under ambient conditions.

@article{Pigulski_2022, abstract = {A supramolecular trilayer nanographene complex consisting of a newly synthesized D3h-symmetric C 54-nanographene trisimide (NTI 1) and two hexabenzocoronenes (HBC) has been obtained by self-assembly. This 1:2 complex is structurally well- defined according to UV/vis and single crystal X-ray studies and exhibits high thermodynamic stability even in polar halogenated solvents. Complexation of NTI 1 by two HBC molecules protects the NTI 1 π-surface efficiently from oxygen quenching, thereby leading to a sequestration-induced fluorescence enhancement under ambient conditions.}, added-at = {2022-04-08T09:52:10.000+0200}, author = {Pigulski, Bartłomiej and Shoyama, Kazutaka and Sun, Meng-Jia and Würthner, Frank}, biburl = {https://www.bibsonomy.org/bibtex/250643a1707201c742636f1464a9fc5f8/wuerthner_group}, doi = {10.1021/jacs.2c00142}, interhash = {35942819db2fe0aff46eb09cdcafcfab}, intrahash = {50643a1707201c742636f1464a9fc5f8}, journal = {J. Am. Chem. Soc.}, keywords = {myown}, month = mar, number = 13, pages = {5718--5722}, publisher = {American Chemical Society (ACS)}, timestamp = {2023-05-23T13:05:50.000+0200}, title = {Fluorescence Enhancement by Supramolecular Sequestration of a C54-Nanographene Trisimide by Hexabenzocoronene}, url = {https://doi.org/10.1021%2Fjacs.2c00142}, volume = 144, year = 2022 }