%0 Journal Article %1 RN150 %A Rios, H.E. %A Briones, X.G. %A Urzua, M.D. %A Vargas, V.A. %D 2013 %J Journal of Macromolecular Science Part B-Physics %K 4-alkylbenzene adsorption, aqueous-solution, association, binding, chloride chloroform-water cooperative counterions, dextran dodecyltrimethylammonium dqcauchile effects, hydrophobic interactions, interface, ions, micelles, poly(styrenesulfonate), polyelectrolyte polyelectrolytes, sulfate, sulfonate surfactant water, %N 4 %P 614-622 %R 10.1080/00222348.2012.716334 %T Cooperative Association of P-Alkylbenzene Sulfonates Sodium Salts to Poly-2-(Dimethylamino) Ethylmethacrylate-N-Alkyl Quaternized at the Water/Chloroform Interface %U /brokenurl#<Go to ISI>://WOS:000313621900008 %V 52 %X The association of p-alkyl benzene sulfonate sodium salts with several poly-2-(dimethylamino) ethylmethacrylate-N-alkyl quaternized bromides at the water/chloroform interface was studied. High association percentages were found which increase with both the size of the sulfonate molecule and the length of the polyelectrolyte side chain: octyl, decyl, dodecyl and tetradecyl. The results fit well to the Hill's equation for the association of anionic surfactant to polyelectrolytes. Benzene sulfonate shows an anticooperative behavior for the association, whereas 4-methyl benzene sulfonate and 4-ethylbenzene sulfonate are increasingly cooperative for the association. From the association constants, the standard free energies of transfer from water to the interfacial polyelectrolytes were determined. Their values were a linear function of the number of carbon atoms of the aliphatic residue of the benzene sulfonate molecule ranging from -15.7 kJ/mol of CH2 groups for the octyl polyelectrolyte to -18.9 kJ/mol of CH2 groups for the tetradecyl derivative. These values are similar to those reported for the association of some of these sulfonates molecules with ammonium type cationic micelles. The results for the incremental free energy of transfer by mol of methylene group from water to micelles are in the same order of magnitude as those reported for p-alkyl phenoxides and p-alkylbenzoates to hexadecyltrimethyl ammonium bromide micelles. The results shows that amphipathic counterions as small as 4-ethylbenzenesulfonate are enough to induce a cooperative effect in their association to cationic polyelectrolytes.

@article{RN150, abstract = {The association of p-alkyl benzene sulfonate sodium salts with several poly-2-(dimethylamino) ethylmethacrylate-N-alkyl quaternized bromides at the water/chloroform interface was studied. High association percentages were found which increase with both the size of the sulfonate molecule and the length of the polyelectrolyte side chain: octyl, decyl, dodecyl and tetradecyl. The results fit well to the Hill's equation for the association of anionic surfactant to polyelectrolytes. Benzene sulfonate shows an anticooperative behavior for the association, whereas 4-methyl benzene sulfonate and 4-ethylbenzene sulfonate are increasingly cooperative for the association. From the association constants, the standard free energies of transfer from water to the interfacial polyelectrolytes were determined. Their values were a linear function of the number of carbon atoms of the aliphatic residue of the benzene sulfonate molecule ranging from -15.7 kJ/mol of CH2 groups for the octyl polyelectrolyte to -18.9 kJ/mol of CH2 groups for the tetradecyl derivative. These values are similar to those reported for the association of some of these sulfonates molecules with ammonium type cationic micelles. The results for the incremental free energy of transfer by mol of methylene group from water to micelles are in the same order of magnitude as those reported for p-alkyl phenoxides and p-alkylbenzoates to hexadecyltrimethyl ammonium bromide micelles. The results shows that amphipathic counterions as small as 4-ethylbenzenesulfonate are enough to induce a cooperative effect in their association to cationic polyelectrolytes.}, added-at = {2019-12-04T03:57:35.000+0100}, author = {Rios, H.E. and Briones, X.G. and Urzua, M.D. and Vargas, V.A.}, biburl = {https://www.bibsonomy.org/bibtex/2f5e58611caacc431990666d5838fc7c3/dqcauchile}, doi = {10.1080/00222348.2012.716334}, interhash = {3a20cfe266aa953b4b5a8942128228a2}, intrahash = {f5e58611caacc431990666d5838fc7c3}, issn = {0022-2348}, journal = {Journal of Macromolecular Science Part B-Physics}, keywords = {4-alkylbenzene adsorption, aqueous-solution, association, binding, chloride chloroform-water cooperative counterions, dextran dodecyltrimethylammonium dqcauchile effects, hydrophobic interactions, interface, ions, micelles, poly(styrenesulfonate), polyelectrolyte polyelectrolytes, sulfate, sulfonate surfactant water,}, number = 4, pages = {614-622}, timestamp = {2019-12-04T03:58:17.000+0100}, title = {Cooperative Association of P-Alkylbenzene Sulfonates Sodium Salts to Poly-2-(Dimethylamino) Ethylmethacrylate-N-Alkyl Quaternized at the Water/Chloroform Interface}, type = {Journal Article}, url = {/brokenurl#<Go to ISI>://WOS:000313621900008}, volume = 52, year = 2013 }