%0 Journal Article %1 ISI:000265303500010 %A Notash, Behrouz %A Safari, Nasser %A Abedi, Anita %A Amani, Vahid %A Khavasi, Hamid Reza %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2009 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K - 2'-Dimethyl-4; 2; 4'-bithiazole; One-dimensional X-ray coordination crystal polymer; stacking; structure} {Cadmium; %N 10 %P 1638-1649 %R 10.1080/00958970802672978 %T Cadmium(II) complexes containing 2,2'-dimethyl-4,4'-bithiazole ligand: synthesis, characterization, and crystal structure %V 62 %X Mononuclear and coordination polymer compounds of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) ligand have been prepared by metallation of dm4bt with Cd(NO3)2 4H2O and CdCl2 H2O. The compounds were characterized by IR, 1H NMR, UV-Vis spectroscopy, and X-ray crystallography. The structural study of Cd(dm4bt)2(NO3)2 H2O (1) shows that the complex is a monomeric seven-coordinate (CdN4O3) cadmium(II)-bithiazole system with two bidentate dm4bt and mono and bidentate nitrates. The structure of Cd(dm4bt)Cl2n (2) is a distorted octahedral environment around the cadmium(II) (CdN2Cl4) forming a 1-D coordination polymer as a result of bridging by two chlorides and 2-D structure from - stacking interactions.

@article{ISI:000265303500010, abstract = {{Mononuclear and coordination polymer compounds of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) ligand have been prepared by metallation of dm4bt with Cd(NO3)2 4H2O and CdCl2 H2O. The compounds were characterized by IR, 1H NMR, UV-Vis spectroscopy, and X-ray crystallography. The structural study of {[}Cd(dm4bt)2(NO3)2] H2O (1) shows that the complex is a monomeric seven-coordinate (CdN4O3) cadmium(II)-bithiazole system with two bidentate dm4bt and mono and bidentate nitrates. The structure of {[}Cd(dm4bt)Cl2]n (2) is a distorted octahedral environment around the cadmium(II) (CdN2Cl4) forming a 1-D coordination polymer as a result of bridging by two chlorides and 2-D structure from - stacking interactions.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shaheed Beheshti Univ, Dept Chem, Tehran, Iran. Notash, Behrouz; Safari, Nasser; Amani, Vahid; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran, Iran. Abedi, Anita, Islamic Azad Univ, Dept Chem, N Tehran Branch, Tehran, Iran.}}, article-number = {{PII 908373611}}, author = {Notash, Behrouz and Safari, Nasser and Abedi, Anita and Amani, Vahid and Khavasi, Hamid Reza}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/24f1d4e4bf28e5f0e1d8b2a4637add9b0/hkhavasi}, cited-references = {{Abu-Youssef MAM, 2005, J COORD CHEM, V58, P1377, DOI 10.1080/00958970500241498. Amani V, 2007, POLYHEDRON, V26, P4257, DOI 10.1016/j.poly.2007.05.050. Bach T, 2001, ANGEW CHEM INT EDIT, V40, P3184, DOI 10.1002/1521-3773(20010903)40:17<3184::AID-ANIE3184>3.0.CO;2-7. Banerjee S, 2005, POLYHEDRON, V24, P2963, DOI 10.1016/j.poly.2005.06.038. Banerjee S, 2005, POLYHEDRON, V24, P593, DOI 10.1016/j.poly.2005.01.005. Barnett SA, 2005, DALTON T, P3852, DOI 10.1039/b509294a. Barros-Garcia FJ, 2004, INORG CHIM ACTA, V357, P1457, DOI 10.1016/j.ica.2003.11.015. Burger RM, 1998, CHEM REV, V98, P1153, DOI 10.1021/cr960438a. Cao J, 2003, CHEM MATER, V15, P4424, DOI 10.1021/cm034484k. Chastanet G, 2001, CHEM COMMUN, P819, DOI 10.1039/b100426n. Dong YB, 1999, INORG CHEM, V38, P3056, DOI 10.1021/ic9814569. DREW MGB, 1983, POLYHEDRON, V2, P269, DOI 10.1016/S0277-5387(00)83912-1. Farinas ET, 1996, INORG CHEM, V35, P2637, DOI 10.1021/ic9503139. Hecht S. M., 1979, BLEOMYCIN CHEM BIOCH. Hosseinian A, 2006, Z ANORG ALLG CHEM, V632, P2505, DOI 10.1002/zaac.200600230. Hu CH, 2003, CRYSTENGCOMM, V5, P519, DOI 10.1039/b314522k. HUANG CH, 1980, BIOCHEMISTRY-US, V19, P1761, DOI 10.1021/bi00550a006. Janiak C, 1999, J CHEM SOC DALTON, P3121, DOI 10.1039/a904829d. Janiak C, 2003, DALTON T, P2781, DOI 10.1039/b305705b. Janiak C., 2000, DALTON T, P3885, DOI DOI 10.1039/B0030100. Karmakar R, 2007, INORG CHIM ACTA, V360, P2631, DOI 10.1016/j.ica.2006.12.050. Khavasi HR, 2008, POLYHEDRON, V27, P1848, DOI 10.1016/j.poly.2008.02.029. Liu BX, 2005, ACTA CRYSTALLOGR E, V61, pM2291, DOI 10.1107/S1600536805032071. LIU BX, 2006, ACTA CRYSTALLOGR E, V62, P1439. Liu SX, 2004, ANGEW CHEM INT EDIT, V43, P4738, DOI 10.1002/anie.200460149. Liu WY, 2003, J COMPUT SCI TECHNOL, V18, P56, DOI 10.1007/BF02946651. Luo JH, 2002, POLYHEDRON, V21, P893, DOI 10.1016/S0277-5387(02)00868-9. MACGOWAN DA, 1977, J AM CHEM SOC, V99, P8078. Mahjoub AR, 2002, POLYHEDRON, V21, P197, DOI 10.1016/S0277-5387(01)00986-X. MANDERVILLE RA, 1994, J AM CHEM SOC, V116, P10851, DOI 10.1021/ja00102a087. Mathieu J, 2004, EUR J INORG CHEM, P3172, DOI 10.1002/ejic.200300958. Morsali A, 2003, Z ANORG ALLG CHEM, V629, P1627, DOI 10.1002/zaac.200300039. Nakamato K., 1997, INFRARED RAMAN SPE B. NIEUWENHUYZEN M, 1991, POLYHEDRON, V10, P2111, DOI 10.1016/S0277-5387(00)86130-6. Paul B, 2004, Z ANORG ALLG CHEM, V630, P1650, DOI 10.1002/zaac.200400240. Politis JK, 1999, MACROMOLECULES, V32, P2484, DOI 10.1021/ma981242a. Rice CR, 2003, POLYHEDRON, V22, P755, DOI 10.1016/S0277-5387(02)01406-7. Sheldrick G. M., 1997, SHELX 97 PROGRAM CRY. Shi X, 2005, CRYST GROWTH DES, V5, P341, DOI 10.1021/cg049884e. {[}Anonymous], 2005, X AREA PROGR ACQ AN. {*}STOE CIE GMBH, 2004, X SHAPE CRYST OPT NU. {[}Anonymous], 2005, X RED PROGR DAT RED. Stoe Cie, 2000, X STEP32 CRYST PACK. Suen MC, 2007, J COORD CHEM, V60, P257, DOI 10.1080/00958970600873315. Tian YN, 1996, POLYHEDRON, V15, P2771. UMEZAWA H, 1980, ANTICANCER AGENTS BA. VAMBELLE C, 2003, BIOCHEMISTRY-US, V42, P651. Waalkes MP, 2000, J INORG BIOCHEM, V79, P241, DOI 10.1016/S0162-0134(00)00009-X. Yamamoto T, 1997, CHEM MATER, V9, P1217, DOI 10.1021/cm960601i. Zhou ZX, 2005, POLYMER, V46, P9495, DOI 10.1016/j.polymer.2005.07.047. {[}Anonymous], 1995, INT TABLES XRAY CRYS, VC.}}, doc-delivery-number = {{434VZ}}, doi = {{10.1080/00958970802672978}}, funding-acknowledgement = {{Shahid Beheshti University}}, funding-text = {{We would like to thank Graduate Study Councils of Shahid Beheshti University for financial support.}}, interhash = {4fcaa7ee95a6ee34e955cc96a1e6089f}, intrahash = {4f1d4e4bf28e5f0e1d8b2a4637add9b0}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {- 2'-Dimethyl-4; 2; 4'-bithiazole; One-dimensional X-ray coordination crystal polymer; stacking; structure} {Cadmium;}, keywords-plus = {{2-DIMENSIONAL COORDINATION POLYMERS; MERCURY(II) COMPLEXES; COMPOUND; ZINC(II); ANALOGS; BITHIAZOLES; BLEOMYCIN; CLEAVAGE; BRIDGES; CU}}, language = {{English}}, number = {{10}}, number-of-cited-references = {{51}}, orcid-numbers = {{, Anita/0000-0001-7562-6241}}, pages = {{1638-1649}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{28}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Cadmium(II) complexes containing 2,2'-dimethyl-4,4'-bithiazole ligand: synthesis, characterization, and crystal structure}}, type = {{Article}}, unique-id = {{ISI:000265303500010}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{3}}, volume = {{62}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2009}} }