%0 Journal Article %1 Yu2003 %A Yu, J. C. %A Jiang, Z. T. %A Liu, H. Y. %A Yu, J. G. %D 2003 %I Academic Press Inc Elsevier Science %J Journal Of Colloid And Interface Science %K ADSORPTION; ANATASE; DIOXIDE; ETHANOL; PARTICLES; RUTILE SOLVENTS; STABILIZATION; TIO2; %N 1 %P 97--100 %T Influence of solvation interactions on the zeta potential of titania powders %V 262 %X The influence of solvation interactions on the surface charge of titania powders was studied by means of linear solvation energy relationships (LSER). The zeta potential (ZP) of titania powders and the effect of water content were determined in a series of alcohols, including methanol, ethanol, I-propanol, isopropanol, and 1-butanol. The ZPs against the solvents' 13 LSER descriptors were analyzed by principal component analysis (PCA), cluster analysis, multiple linear regression (MLR), and stepwise multiple regression (SMR). Very good correlation between ZP and LSER parameter was obtained. One LSER parameter, relative dielectric constant, epsilon, was used to establish the LSER equation. The ZP of titania powders in pure alcohols can be reasonably calculated by an empirical formula: ZP = 13.43 - 213.63 . 1/epsilon. The results show that epsilon is the most important factor governing the ZP of titania powders. The results also suggest that the effect of solvation interactions on ZP is a result of the electrostatic interactions between powders and solvents. (C) 2003 Elsevier Science (USA). All rights reserved.

@article{Yu2003, abstract = {The influence of solvation interactions on the surface charge of titania powders was studied by means of linear solvation energy relationships (LSER). The zeta potential (ZP) of titania powders and the effect of water content were determined in a series of alcohols, including methanol, ethanol, I-propanol, isopropanol, and 1-butanol. The ZPs against the solvents' 13 LSER descriptors were analyzed by principal component analysis (PCA), cluster analysis, multiple linear regression (MLR), and stepwise multiple regression (SMR). Very good correlation between ZP and LSER parameter was obtained. One LSER parameter, relative dielectric constant, epsilon, was used to establish the LSER equation. The ZP of titania powders in pure alcohols can be reasonably calculated by an empirical formula: ZP = 13.43 - 213.63 . 1/epsilon. The results show that epsilon is the most important factor governing the ZP of titania powders. The results also suggest that the effect of solvation interactions on ZP is a result of the electrostatic interactions between powders and solvents. (C) 2003 Elsevier Science (USA). All rights reserved.}, added-at = {2009-02-13T13:09:53.000+0100}, author = {Yu, J. C. and Jiang, Z. T. and Liu, H. Y. and Yu, J. G.}, biburl = {https://www.bibsonomy.org/bibtex/2c7c126e2d72cce97a98504fc6b9e65b5/almailer}, c1 = {Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China.EOLEOLChinese Univ Hong Kong, Environm Sci Program, Shatin, Hong Kong, Peoples R China.EOLEOLTianjin Univ Commerce, Dept Food Sci & Engn, Tianjin 300400, Peoples R China.}, de = {titania powders; alcohols; zeta potential; linear solvation energyEOLEOLrelationships (LSER)}, description = {Initial Import}, di = {10.1016/S0021-9797(03)00195-4}, file = {:Yu2003.pdf:PDF}, ga = {682AY}, interhash = {55730073a3c53c7360b09f1227780e57}, intrahash = {c7c126e2d72cce97a98504fc6b9e65b5}, j9 = {J COLLOID INTERFACE SCI}, ji = {J. Colloid Interface Sci.}, journal = {Journal Of Colloid And Interface Science}, keywords = {ADSORPTION; ANATASE; DIOXIDE; ETHANOL; PARTICLES; RUTILE SOLVENTS; STABILIZATION; TIO2;}, la = {English}, month = {June}, nr = {18}, number = 1, owner = {s0346678}, pa = {525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA}, pages = {97--100}, pg = {4}, pi = {SAN DIEGO}, publisher = {Academic Press Inc Elsevier Science}, rp = {Yu, JC, Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples REOLEOLChina.}, sc = {Chemistry, Physical}, sn = {0021-9797}, tc = {6}, timestamp = {2009-02-13T13:09:55.000+0100}, title = {Influence of solvation interactions on the zeta potential of titania powders}, ut = {ISI:000183069100012}, volume = 262, year = 2003 }