Article,

Adsorption sites of CO on Pt (111)

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Applied Physics A: Materials Science & Processing, (1977)
DOI: 10.1007/BF00882473

Abstract

The surface vibrations of CO adsorbed on Pt(111) single crystal surfaces at 320 K have been studied by electron-energy-loss spectroscopy. At low coverages two vibration modes at 58 and \sim260 meV are observed. For exposures >0.2 Langmuir two additional modes at 45 and 232 meV develop. Considering also the observed LEED structures these vibrations are attributed to CO molecules being adsorbed upright in on-top and bridge sites, respectively.

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