Abstract
We describe the facile preparation of novel, optically active nitridomanganese(V)
complexes which serve as reagents for the electrophilic amination
of sulfides. This amination method has several appealing features,
including: i) the facile preparation of large quantities of the
starting nitridomanganese reagent 3, ii) the preparation of acylsulfilimines
2 in optically active form, and iii) the mild reaction conditions
employed.
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