%0 Journal Article %1 ISI:000302771800012 %A Hadadzadeh, Hassan %A Mansouri, Ghobad %A Rezvani, Ali Reza %A Khavasi, Hamid Reza %C 233 SPRING ST, NEW YORK, NY 10013 USA %D 2012 %I SPRINGER/PLENUM PUBLISHERS %J JOURNAL OF CHEMICAL CRYSTALLOGRAPHY %K 1,10-Phenanthroline-5,6-dione; 1,10-Phenanthroline} Crystal Cyclic Nickel(II) complex; structure; voltammetry; {Co-crystal; %N 5 %P 486-493 %R 10.1007/s10870-011-9992-y %T A Novel 1:1 Co-Crystal of Bis(1,10-Phenanthroline)(1,10-Phenanthroline-5,6-Dione)Nickel(II) Hexafluorophosphate and Tris(1,10-Phenanthroline)Nickel(II) Hexafluorophosphate Complexes, Ni(phen)(2)(phen-dione) Ni(phen)(3) (PF6)(4) %V 42 %X The purpose of this study was to investigate whether co-crystals form by simply mixing pure solutions of Ni(phen)(3)(PF6)(2) and Ni(phen)(2)(phen-dione)(PF6)(2) where phen is 1,10-phenanthroline and phen-dione is 1,10-phenanthroline-5,6-dione. The 1:1 cocrystal, Ni(phen)(2)(phen-dione)Ni(phen)(3)(PF6)(4)center dot CH3CN has been characterized by elemental analysis, IR, paramagnetic NMR, and UV-vis spectroscopies, cyclic voltammetry, and single crystal X-ray structure analysis. The title complex crystallized in triclinic crystal system (z = 2) with space group of PA <<, a = 13.201(2) , b = 14.782(3) , c = 22.294(4) , alpha = 81.575(15)(o), beta = 88.756(15)(o), gamma = 88.032(15)(o) and V = 4300.1(14) (3). A careful inspection of the packing pattern in the lattice reveals that non-covalent interactions of three different types, viz. C-H center dot center dot center dot F, C=O center dot center dot center dot H-C and C-H center dot center dot center dot pi interactions, are active in the lattice. The coordination around the Ni(II) centers is a distorted octahedral, with bite angles of 78.3-79.8(o) for the chelating phen and phen-dione ligands. Cyclic voltammetry of this co-crystal shows that the Ni(III/II) couple is quasi-reversible. The effective magnetic moment (mu(eff)) of the co-crystal was measured to be 2.87 BM per Ni(II) ion by Evans method. The magnitude of mu(eff) is consistent with magnetic moment for octahedral Ni(II) complexes.

@article{ISI:000302771800012, abstract = {{The purpose of this study was to investigate whether co-crystals form by simply mixing pure solutions of {[}Ni(phen)(3)](PF6)(2) and {[}Ni(phen)(2)(phen-dione)](PF6)(2) where phen is 1,10-phenanthroline and phen-dione is 1,10-phenanthroline-5,6-dione. The 1:1 cocrystal, {[}Ni(phen)(2)(phen-dione)]{[}Ni(phen)(3)](PF6)(4)center dot CH3CN has been characterized by elemental analysis, IR, paramagnetic NMR, and UV-vis spectroscopies, cyclic voltammetry, and single crystal X-ray structure analysis. The title complex crystallized in triclinic crystal system (z = 2) with space group of PA <<, a = 13.201(2) , b = 14.782(3) , c = 22.294(4) , alpha = 81.575(15)(o), beta = 88.756(15)(o), gamma = 88.032(15)(o) and V = 4300.1(14) (3). A careful inspection of the packing pattern in the lattice reveals that non-covalent interactions of three different types, viz. C-H center dot center dot center dot F, C=O center dot center dot center dot H-C and C-H center dot center dot center dot pi interactions, are active in the lattice. The coordination around the Ni(II) centers is a distorted octahedral, with bite angles of 78.3-79.8(o) for the chelating phen and phen-dione ligands. Cyclic voltammetry of this co-crystal shows that the Ni(III/II) couple is quasi-reversible. The effective magnetic moment (mu(eff)) of the co-crystal was measured to be 2.87 BM per Ni(II) ion by Evans method. The magnitude of mu(eff) is consistent with magnetic moment for octahedral Ni(II) complexes.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{233 SPRING ST, NEW YORK, NY 10013 USA}}, affiliation = {{Hadadzadeh, H (Reprint Author), Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran. Hadadzadeh, Hassan, Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran. Mansouri, Ghobad; Rezvani, Ali Reza, Univ Sistan \& Baluchestan, Dept Chem, Zahedan, Iran. Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, Tehran, Iran.}}, author = {Hadadzadeh, Hassan and Mansouri, Ghobad and Rezvani, Ali Reza and Khavasi, Hamid Reza}, author-email = {{hadad@cc.iut.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2ce1560e6f343806092f46daf5b1b8716/hkhavasi}, cited-references = {{Allen FH, 2002, ACTA CRYSTALLOGR B, V58, P407, DOI 10.1107/S0108768102004895. Anderson P. O., 1973, J CHEM SOC DA, P1237. Balzani V, 1996, CHEM REV, V96, P759, DOI 10.1021/cr941154y. Bond A.D., 2002, SUPRAMOLECULAR ORG M. BOYS D, 1984, ACTA CRYSTALLOGR C, V40, P1359, DOI 10.1107/S0108270184007964. Calderazzo F, 2002, INORG CHIM ACTA, V330, P136, DOI 10.1016/S0020-1693(01)00711-3. Calmuschi B, 2004, DALTON T, P1852, DOI 10.1039/b316548e. Chiarella RA, 2007, CRYST GROWTH DES, V7, P1223, DOI 10.1021/cg070218y. Chou CC, 2005, INORG CHEM, V44, P628, DOI 10.1021/ic048854y. DEACON GB, 1979, AUST J CHEM, V32, P2195. Desiraju G., 1999, WEAK HYDROGEN BOND I. 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Wang CG, 2004, J MOL STRUCT, V702, P1, DOI 10.1016/j.molstruc.2004.06.003. Xiong Y, 2002, J CHEM CRYSTALLOGR, V32, P219, DOI 10.1023/A:1020292821315. YAMADA M, 1992, B CHEM SOC JPN, V65, P1006, DOI 10.1246/bcsj.65.1006. Zaworotko MJ, 2007, J CHEM CRYSTALLOGR, V37, P219, DOI 10.1007/s10870-006-9174-5. Zukerman-Schpector J, 2008, Z KRISTALLOGR, V223, P233, DOI 10.1524/zkri.2008.0021.}}, doc-delivery-number = {{925OX}}, doi = {{10.1007/s10870-011-9992-y}}, funding-acknowledgement = {{Isfahan University of Technology (IUT); University of Sistan and Baluchestan (USB)}}, funding-text = {{Support by Isfahan University of Technology (IUT) and University of Sistan and Baluchestan (USB) is gratefully acknowledged.}}, interhash = {62da3ae0e78236593d5197aa8832ad77}, intrahash = {ce1560e6f343806092f46daf5b1b8716}, issn = {{1074-1542}}, journal = {{JOURNAL OF CHEMICAL CRYSTALLOGRAPHY}}, journal-iso = {{J. Chem. Crystallogr.}}, keywords = {1,10-Phenanthroline-5,6-dione; 1,10-Phenanthroline} Crystal Cyclic Nickel(II) complex; structure; voltammetry; {Co-crystal;}, keywords-plus = {{GEOMETRICAL-ISOMERS; MAGNETIC-PROPERTIES; TRANSITION-METALS; COCRYSTALS; 1,10-PHENANTHROLINE-5,6-DIONE; PHASE; SALT; DIAGRAMS; NETWORKS; IRON(II)}}, language = {{English}}, month = {{MAY}}, number = {{5}}, number-of-cited-references = {{63}}, pages = {{486-493}}, publisher = {{SPRINGER/PLENUM PUBLISHERS}}, research-areas = {{Crystallography; Spectroscopy}}, researcherid-numbers = {{G, Neela/H-3016-2014}}, times-cited = {{0}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{A Novel 1:1 Co-Crystal of Bis(1,10-Phenanthroline)(1,10-Phenanthroline-5,6-Dione)Nickel(II) Hexafluorophosphate and Tris(1,10-Phenanthroline)Nickel(II) Hexafluorophosphate Complexes, {[}Ni(phen)(2)(phen-dione)] {[}Ni(phen)(3)] (PF6)(4)}}, type = {{Article}}, unique-id = {{ISI:000302771800012}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{15}}, volume = {{42}}, web-of-science-categories = {{Crystallography; Spectroscopy}}, year = {{2012}} }